Shape memory alloy foils that are appropriately patterned are cycled between two different metal foil geometries resulting in two different terahertz (THz) plasmonic responses. This is accomplished by using patterned foils of a nickel–titanium alloy (Nitinol) that switches between the martensite phase below 31 °C, yielding one physical geometry, and the austenite phase, when the foil is heated above 51 °C, yielding a second physical geometry. In order to enable this reproducible switching, the sample is initially put through a two‐way training procedure, through which the two different desired physical geometries are imprinted. Specifically, the metal foils are trained to switch between a sinusoidal corrugation, either 1D or 2D, at close to room temperature and a flat metal sheet above the austenite phase transition temperature. The foils are found to switch reproducibly between geometries over at least 100 thermal cycles. Using THz time‐domain spectroscopy, the transmission properties of the foils are measured as a function of incident polarization and foil geometry. The changes in spectrum are explained qualitatively and through numerical simulation.
more » « less- NSF-PAR ID:
- 10034326
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Advanced Optical Materials
- Volume:
- 5
- Issue:
- 7
- ISSN:
- 2195-1071
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
Oscillating foil turbines can be utilized to extract hydrokinetic energy from tidal or river flows. When foils are placed in arrays, the reduced velocity between foils and the unsteady disturbances associated with the leading foil motion both affect the performance of downstream foils. To compare the performance between foils, a wide range of kinematics is numerically explored in a two-foil tandem configuration with matching strokes, but varying the inter-foil phase angle and spacing. The effects of the wake on the trailing foil performance are quantified by evaluating the difference between the normalized power extracted by each foil. The difference in normalized power extraction is a function of the wake phase parameter, Φ, and ranges from -65% to +6%, depending on the kinematic regime. It is also determined that the difference in normalized power is dominated by the pressure contribution from the heave stroke, whereas the viscous components are negligible. In general, these differences illustrate the unsteady effects within the wake of the first foil, and the various interaction modes of the downstream foil. These trends can be used to estimate power in other array configurations and provide a more robust model for wake-foil interactions for energy harvesting.more » « less
-
Abstract Aluminum is an attractive candidate for replacing graphite anodes in lithium‐ion batteries because of its high specific capacity and the potential for direct use as foil. However, achieving reversible reaction of aluminum is challenging due to volume changes, SEI formation, and sluggish ion transport. Although prior work has investigated electrochemical transformation behavior of aluminum, the effects of key variables, including areal capacity per cycle and alloy composition, are not well understood. Here, we carry out comprehensive electrochemical testing to benchmark the performance of two different aluminum foils (99.999 % Al and Al 8111). We find that for constant thickness, both foil compositions exhibit a power‐law dependence of cycle life on the lithiated areal capacity per cycle, revealing that degradation is significantly more rapid at higher areal capacities. This behavior is interpreted as an “electrochemical fatigue” mechanism, in analogy to mechanical fatigue. Additionally, the alloy composition was found to strongly affect the Coulombic efficiency (CE), with high‐purity foils exhibiting higher initial CE but reduced long‐term stability. Finally,
operando optical microscopy revealed different spatiotemporal reaction mechanisms amongst the different materials. This improved understanding of aluminum foil anodes paves the way for efforts to engineer aluminum‐based foils with enhanced stability. -
Optically controlled RF switches with a novel non-contact device architecture that achieves high performance in the millimeterwave-to-terahertz (mmW-THz) region are proposed and investigated through simulation. The significant change in conductivity in semiconductors caused by photogenerated carriers is used to develop RF switches having very high performance. By including a thin layer of insulator between the active semiconductor material and the metal contacts, the carrier concentration can be enhanced over that of conventional devices. For a prototype demonstration, G-band coplanar waveguide-based optical switches (using Si and Ge as active materials) with different contact geometries have been modeled and simulated. The proposed switches outperform both conventional solid-state switches and phase-change material-based switches in the switch figure-of-merit, and are promising for developing a novel class of tunable and reconfigurable mmW-THz circuits for advanced sensing, imaging, and communication.
-
Abstract A gas metal-directed energy deposition process was used to fabricate builds using two commercial weld fillers used in power generation applications, 16-8-2 and 316H. Microstructure stability and mechanical properties were investigated through room-temperature and elevated temperature tensile testing and creep testing at 650°C, 750°C, and 825°C. 16-8-2 exhibited reduced austenite stability which resulted in athermal martensite formation after aging at 650°C for 1000 h and strain-induced martensite formation during room-temperature tensile testing. 316H exhibited relatively higher austenite stability due to increased alloying content, resulting in no athermal martensite or strain-induced martensite. Due to lower austenite stability, ferrite formed during creep at 650°C in 16-8-2, which resulted in reduced creep life and lower creep ductility compared to 316H. At 750°C and 825°C, when ferrite is no longer thermodynamically stable, 16-8-2 exhibited longer creep life and similar creep ductility as 316H. The formation of ferrite in 16-8-2 appears to have a greater impact on creep performance than the formation of embrittling topologically close-packed phases like the σ phase, as 316H exhibited superior creep performance while predicted to form 14 vol.% σ phase at 650°C.
-
Numerical studies are presented on the propulsive performance and vortex dynamics of multiple hydrofoils pitching in an in-line configuration. The study is motivated by the quest to understand the hydrodynamics of multiple fin–fin interactions in fish swimming. Using the flow conditions (Strouhal and Reynolds numbers) obtained from a solitary pitching foil of zero net thrust, the effect of phase differences between neighboring foils on the hydrodynamic performance is examined both in position-fixed two- and three-foil systems at Reynolds number Re = 500. It is found that the threefoil system achieves a thrust enhancement up to 118% and an efficiency enhancement up to 115% compared to the two-foil system. Correspondingly, the leading-edge vortex (LEV) and the trailing-edge vortex (TEV) of the hindmost foil combine to form a ‘2P’ wake structure behind the three-foil system with the optimal phase differences instead of a ‘2S’ wake, a coherent wake pattern observed behind the optimal two-foil system. The finding suggests that a position-fixed three-foil system can generate a ‘2P’ wake to achieve the maximum thrust production and propulsive efficiency simultaneously by deliberately choosing the undulatory phase for each foil. When increasing Reynolds number to 1000, though the maximum thrust and propulsive efficiency are not achieved simultaneously, the most efficient case still produces more thrust than most of the other cases. Besides, the study on the effects of three-dimensionality shows that when the foils have a larger aspect ratio, the three-foil system has a better hydrodynamic performance, and it follows a similar trend as the two-dimensional (2D) foil system. This work aids in the future design of high-performance underwater vehicles with multiple controlled propulsion elements.more » « less