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1. Climate controls on coupled processes of chemical weathering, bioturbation, and sediment transport across hillslopes: Climate, weathering, bioturbation and sediment transport on hillslopes

   https://doi.org/10.1002/esp.4337  

   Wackett, A.A. ; Yoo, K. ; Amundson, R. ; Heimsath, A.M. ; Jelinski, N.A. ( June 2018 , Earth Surface Processes and Landforms)
2. A low‐dimensional model of bedrock weathering and lateral flow coevolution in hillslopes: 2. Controls on weathering and permeability profiles, drainage hydraulics, and solute export pathways

   https://doi.org/10.1002/hyp.13385  

   Harman, Ciaran J. ; Cosans, Cassandra L. ( February 2019 , Hydrological Processes)

   The advance of a chemical weathering front into the bedrock of a hillslope is often limited by the rate weathering products that can be carried away, maintaining chemical disequilibrium. If the weathering front is within the saturated zone, groundwater flow downslope may affect the rate of transport and weathering—however, weathering also modifies the rock permeability and the subsurface potential gradient that drives lateral groundwater flow. This feedback may help explain why there tends to be neither “runaway weathering” to great depth nor exposed bedrock covering much of the earth and may provide a mechanism for weathering front advance to keep pace with incision of adjacent streams into bedrock. This is the second of a two‐part paper exploring the coevolution of bedrock weathering and lateral flow in hillslopes using a simple low‐dimensional model based on hydraulic groundwater theory. Here, we show how a simplified kinetic model of 1‐D rock weathering can be extended to consider lateral flow in a 2‐D hillslope. Exact and approximate analytical solutions for the location and thickness of weathering within the hillslope are obtained for a number of cases. A location for the weathering front can be found such that lateral flow is able to export weathering products at the rate required to keep pace with stream incision at steady state. Three pathways of solute export are identified: “diffusing up,” where solutes diffuse up and away from the weathering front into the laterally flowing aquifer; “draining down,” where solutes are advected primarily downward into the unweathered bedrock; and “draining along,” where solutes travel laterally within the weathering zone. For each pathway, a different subsurface topography and overall relief of unweathered bedrock within the hillslope is needed to remove solutes at steady state. The relief each pathway requires depends on the rate of stream incision raised to a different power, such that at a given incision rate, one pathway requires minimal relief and, therefore, likely determines the steady‐state hillslope profile.

    

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3. The evolution of lithium isotope signatures in fluids draining actively weathering hillslopes

   https://doi.org/10.1016/j.epsl.2021.116988  

   Golla, Jon K. ; Kuessner, Marie L. ; Henehan, Michael J. ; Bouchez, Julien ; Rempe, Daniella M. ; Druhan, Jennifer L. ( August 2021 , Earth and Planetary Science Letters)
4. A low‐dimensional model of bedrock weathering and lateral flow coevolution in hillslopes: 1. Hydraulic theory of reactive transport

   https://doi.org/10.1002/hyp.13360  

   Harman, Ciaran J. ; Kim, Minseok ( January 2019 , Hydrological Processes)

   This is the first of a two‐part paper exploring the coevolution of bedrock weathering and lateral flow in hillslopes using a simple low‐dimensional model based on hydraulic groundwater theory (also known as Dupuit or Boussinesq theory). Here, we examine the effect of lateral flow on the downward fluxes of water and solutes through perched groundwater at steady state. We derive analytical expressions describing the decline in the downward flux rate with depth. Using these, we obtain analytical expressions for water age in a number of cases. The results show that when the permeability field is homogeneous, the spatial structure of water age depends qualitatively on a single dimensionless number, Hi. This number captures the relative contributions to the lateral hydraulic potential gradient of the relief of the lower‐most impermeable boundary (which may be below the weathering front within permeable or incipiently weathered bedrock) and the water table. A “scaled lateral symmetry” exists when Hi is low: age varies primarily in the vertical dimension, and variations in the horizontal dimensionxalmost disappear when the vertical dimensionzis expressed as a fractionz/H(x) of the laterally flowing system thicknessH(x). Taking advantage of this symmetry, we show how the lateral dimension of the advection–diffusion‐reaction equation can be collapsed, yielding a 1‐D vertical equation in which the advective flux downward declines with depth. The equation holds even when the permeability field is not homogeneous, as long as the variations in permeability have the same scaled lateral symmetry structure. This new 1‐D approximation is used in the accompanying paper to extend chemical weathering models derived for 1‐D columns to hillslope domains.

    

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5. Limited Carbon Cycle Response to Increased Sulfide Weathering Due to Oxygen Feedback

   https://doi.org/10.1029/2021GL094589  

   Maffre, Pierre ; Swanson‐Hysell, Nicholas L. ; Goddéris, Yves ( October 2021 , Geophysical Research Letters)