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Title: Synthesis and Characterization of 1,2-Azaborine-Containing Phosphine Ligands: A Comparative Electronic Structure Analysis: Synthesis and Characterization of 1,2-Azaborine-Containing Phosphine Ligands: A Comparative Electronic Structure Analysis
NSF-PAR ID:
10035121
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  ;  ;  ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
European Journal of Inorganic Chemistry
Volume:
2017
Issue:
15
ISSN:
1434-1948
Page Range / eLocation ID:
2207 to 2210
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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    A rare-earth-containing compound, ytterbium aluminium antimonide, Yb 3 AlSb 3 (Ca 3 AlAs 3 -type structure), has been successfully synthesized within the Yb–Al–Sb system through flux methods. According to the Zintl formalism, this structure is nominally made up of (Yb 2+ ) 3 [(Al 1− )( 1b – Sb 2− ) 2 ( 2b – Sb 1− )], where 1b and 2b indicate 1-bonded and 2-bonded, respectively, and Al is treated as part of the covalent anionic network. The crystal structure features infinite corner-sharing AlSb 4 tetrahedra, [AlSb 2 Sb 2/2 ] 6− , with Yb 2+ cations residing between the tetrahedra to provide charge balance. Herein, the synthetic conditions, the crystal structure determined from single-crystal X-ray diffraction data, and electronic structure calculations are reported. 
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