More Like this

1. Blue-phosphorescent bis-cyclometalated iridium complexes with aryl isocyanide ancillary ligands

   https://doi.org/10.1016/j.poly.2019.114332  

   Cañada, Louise M. ; Kölling, Johanna ; Teets, Thomas S. ( March 2020 , Polyhedron)
2. A rare isocyanide derived from an unprecedented neutral yttrium( ii ) bis(amide) complex

   https://doi.org/10.1039/d3sc00171g  

   Jena, Rashmi ; Benner, Florian ; Delano, Francis ; Holmes, Daniel ; McCracken, John ; Demir, Selvan ; Odom, Aaron L. ( April 2023 , Chemical Science)

   A room temperature stable Y(ii)bis(amide) has been prepared and fully characterized. The complex reacts withtert-butylisocyanide to make a rare example of a transition metal isocyanide, CN–Y(NHAr*)₂.

    

   more » « less
3. Stepwise Preparation of meso -Tetraphenyl- and meso -Tetrakis(4-trifluoromethylphenyl)bacteriodilactones and their Zinc(II) and Palladium(II) Complexes: Stepwise Preparation of meso -Tetraphenyl- and meso -Tetrakis(4-trifluoromethylphenyl)bacteriodilactones and their Zinc(II) and Palladium(II) Complexes

   https://doi.org/10.1002/ejoc.201901727  

   Brückner, Christian ; Atoyebi, Adewole O. ; Girouard, Derek ; Lau, Kimberly S. F. ; Akhigbe, Joshua ; Samankumara, Lalith ; Damunupola, Dinusha ; Khalil, Gamal E. ; Gouterman, Martin ; Krause, Jeanette A. ; et al ( January 2020 , European Journal of Organic Chemistry)
4. Deprotonation, Chloride Abstraction, and Dehydrohalogenation as Synthetic Routes to Bis-Pyrazolate Pyridyl Iron(II) Complexes: Deprotonation, Chloride Abstraction, and Dehydrohalogenation as Synthetic Routes to Bis-Pyrazolate Pyridyl Iron(II) Complexes

   https://doi.org/10.1002/ejic.201700558  

   Cook, Brian J. ; Polezhaev, Alexander V. ; Chen, Chun-Hsing ; Pink, Maren ; Caulton, Kenneth G. ( September 2017 , European Journal of Inorganic Chemistry)
5. A Systematic Electrochemical Investigation of a Dimethylamine Cosolvent-Assisted Nonaqueous Zinc(II) Bis(trifluoromethylsulfonyl)imide Electrolyte

   https://doi.org/10.1149/1945-7111/abe9cb  

   Asselin, Genevieve M. ; Paden, Olivia ; Qiu, Weiqi ; Yang, Zicheng ; Sa, Niya ( March 2021 , Journal of The Electrochemical Society)

   The development of the multivalent electrolytes is a critical component to advance polyvalent energy storage technology. In this work, a new and simple nonaqueous zinc electrolyte is developed and investigated where a secondary amine is introduced as a cosolvent. The addition of dimethylamine (DMA) as a cosolvent in THF facilitates the solubilization of Zinc (II) bis(trifluoromethanesulfonyl)imde (Zn(TFSI)₂) and results in a homogeneous electrolyte with reversible plating of zinc achieved at high coulombic efficiencies. The electrochemical properties of the developed electrolyte and the effects of the cosolvent and salt concentrations are systematically investigated. It was found that increasing the ratio of the cosolvent DMA in THF for a Zn(TFSI)₂electrolyte leads to more facile kinetics, better ion solubilization, and higher ion mobility evidenced by up a significant increase in conductivity as well as the plating/stripping current densities. Increased Zn(TFSI)₂salt concentration in a 2.0 M DMA in THF solvent mixture not only leads to a higher current density and conductivity, but also a higher molar conductivity due to a redissociation mechanism. The findings in this study are relevant and important to further understand and characterize multivalent electrolytes from a simple and effective electrolyte design strategy.

    

   more » « less