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Title: A Terminal Fluoride Ligand Generates Axial Magnetic Anisotropy in Dysprosium Complexes
Abstract

The first dysprosium complexes with a terminal fluoride ligand are obtained as air‐stable compounds. The strong, highly electrostatic dysprosium–fluoride bond generates a large axial crystal‐field splitting of theJ=15/2 ground state, as evidenced by high‐resolution luminescence spectroscopy and correlated with the single‐molecule magnet behavior through experimental magnetic susceptibility data and ab initio calculations.

 
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NSF-PAR ID:
10049649
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  ;  ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
Angewandte Chemie
Volume:
130
Issue:
7
ISSN:
0044-8249
Page Range / eLocation ID:
p. 1951-1956
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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