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Title: Synthesis of Trifluoromethyl Tetrafluoro-λ 6 -sulfanyl-Substituted Alkenes, Ketones, and Acids: Polar Hydrophobic Building Blocks: Synthesis of Trifluoromethyl Tetrafluoro-λ 6 -sulfanyl-Substituted Alkenes, Ketones, and Acids: Polar Hydrophobic Building Blocks
Award ID(s):
1464936 0342660 1429329
PAR ID:
10051533
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
European Journal of Organic Chemistry
Volume:
2018
Issue:
6
ISSN:
1434-193X
Page Range / eLocation ID:
772 to 780
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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  1. null (Ed.)
    Site specific introduction of the polar hydrophobic trifluoromethyl-λ 6 -tetrafluorosulfanyl (CF 3 SF 4 ) group can effectively control the secondary structure of a heptapeptide, the minimum repeat unit of an α-helix. The structural influence of CF 3 SF 4 -containing amino acid on the heptapeptide was established using NMR methods. 
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