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   Osumi, Yuki; Liu, Chengwei; Szostak, Michal (October 2017, Organic & biomolecular chemistry)

   The palladium-catalyzed Suzuki-Miyaura cross-coupling of Nacylsuccinimides as versatile acyl-transfer reagents via selective amide N–C bond cleavage is reported. The method is user-friendly since it employs commercially-available, air-stable reagents and catalysts. The cross-coupling is enabled by half-twist of the amide bond in N-acylsuccinimides. These highly effective, crystalline acyltransfer reagents present major advantages over perpendicularly twisted N-acylglutarimides, including low price of the succinimide activating ring, selective metal insertion under redox neutral conditions and high stability of the amide bond towards reaction conditions. Mechanistic studies indicate that oxidative addition is the rate limiting step in this widely applicable protocol. 

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2. Amide N–C Bond Activation: A Graphical Overview of Acyl and Decarbonylative Coupling

   https://doi.org/10.1055/a-2035-6733  

   Liu, Chengwei; Szostak, Michal (January 2023, SynOpen)

   Abstract This Graphical Review provides an overview of amide bond activation achieved by selective oxidative addition of the N–C(O) acyl bond to transition metals and nucleophilic acyl addition, resulting in acyl and decarbonylative coupling, together with key mechanistic details pertaining to amide bond distortion underlying this reactivity manifold. 

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3. Evaluation of Cyclic Amides as Activating Groups in N–C Bond Cross-Coupling: Discovery of N -Acyl-δ-valerolactams as Effective Twisted Amide Precursors for Cross-Coupling Reactions

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   Rahman, Md. Mahbubur; Pyle, Daniel J.; Bisz, Elwira; Dziuk, Błażej; Ejsmont, Krzysztof; Lalancette, Roger; Wang, Qi; Chen, Hao; Szostak, Roman; Szostak, Michal (August 2021, The Journal of Organic Chemistry)
4. N -Acyl-glutarimides: Effect of Glutarimide Ring on the Structures of Fully Perpendicular Twisted Amides and N–C Bond Cross-Coupling

   https://doi.org/10.1021/acs.joc.0c00227  

   Rahman, Md. Mahbubur; Liu, Chengwei; Bisz, Elwira; Dziuk, Błażej; Lalancette, Roger; Wang, Qi; Chen, Hao; Szostak, Roman; Szostak, Michal (March 2020, The Journal of Organic Chemistry)
5. Twisted N -Acyl-hydantoins: Rotationally Inverted Urea-Imides of Relevance in N–C(O) Cross-coupling

   https://doi.org/10.1021/acs.joc.8b02691  

   Szostak, Roman; Liu, Chengwei; Lalancette, Roger; Szostak, Michal (November 2018, The Journal of Organic Chemistry)