A covalent adaptable network (CAN) with high glass transition temperature (
We have developed a photoinduced copper‐catalyzed alkylation of terminal alkynes with primary, secondary, or tertiary alkyl iodides as electrophiles. The reaction has a broad substrate scope and can be successfully performed in the presence of ester, nitrile, aryl halide, ketone, sulfonamide, epoxide, alcohol, and amide functional groups. The alkylation is promoted by blue light (
- NSF-PAR ID:
- 10056545
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Angewandte Chemie International Edition
- Volume:
- 57
- Issue:
- 19
- ISSN:
- 1433-7851
- Page Range / eLocation ID:
- p. 5492-5496
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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