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  • Unusual Coexistence of Nickel(II) and Nickel(IV) in the Quadruple Perovskite Ba 4 Ni 2 Ir 2 O 12 Containing Ir 2 NiO 12 Mixed-Metal-Cation Trimers
Title: Unusual Coexistence of Nickel(II) and Nickel(IV) in the Quadruple Perovskite Ba 4 Ni 2 Ir 2 O 12 Containing Ir 2 NiO 12 Mixed-Metal-Cation Trimers
Award ID(s):
1655740
PAR ID:
10057708
Author(s) / Creator(s):
; ; ;
Date Published:
Journal Name:
Inorganic Chemistry
Volume:
57
Issue:
6
ISSN:
0020-1669
Page Range / eLocation ID:
2973 to 2976
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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    Abstract Simple access to aryl sulfinates from aryl iodides and bromides is reported using an inexpensive Ni‐electrocatalytic protocol. The reaction exhibits a broad scope, uses stock solution of simple SO2as sulfur source, and can be scaled up in batch and recycle flow settings. The limitations of this reaction are clearly shown and put into context by benchmarking with state‐of‐the‐art Pd‐based methods. 
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