Recent Developments in C–H Activation for Materials Science in the Center for Selective C–H Activation
- Award ID(s):
- 1700982
- NSF-PAR ID:
- 10058362
- Date Published:
- Journal Name:
- Molecules
- Volume:
- 23
- Issue:
- 4
- ISSN:
- 1420-3049
- Page Range / eLocation ID:
- 922
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract Described for the first time is that carbon dioxide (CO2) can be successfully inserted into aryl C−H bonds of the backbone of a metal–organic framework (MOF) to generate free carboxylate groups, which serve as Brønsted acid sites for efficiently catalyzing the methanolysis of epoxides. The work delineates the very first example of utilizing CO2for heterogeneous C−H activation and carboxylation reactions on MOFs, and opens a new avenue for CO2chemical transformations under mild reaction conditions.