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1. Synthesis and Characterization of Non-Aqueous [Tc X M-PW 11 O 39 ] n - with M = O, N: Comparing Tc V and Tc VI in Metal Oxide Matrices: Synthesis and Characterization of Non-Aqueous [Tc X M-PW 11 O 39 ] n - with M = O, N: Comparing Tc V and Tc VI in Metal Oxide Matrices

   https://doi.org/10.1002/ejic.201900864  

   Burton-Pye, Benjamin P. ; Dembowski, Mateusz ; Lukens, Jr., Wayne W. ; Cruz, Anthony ; Althour, Alrasheed ; Lopez, Gustavo E. ; Salcedo, Ramsey ; Gallagher, Colleen M. B. ; McGregor, Donna ; Francesconi, Lynn C. ( November 2019 , European Journal of Inorganic Chemistry)
2. White light emission from co-doped La 2 Hf 2 O 7 nanoparticles with suppressed host → Eu 3+ energy transfer via a U 6+ co-dopant

   https://doi.org/10.1039/D1QI00134E  

   Gupta, Santosh K. ; Modak, Brindaban ; Modak, Pampa ; Mao, Yuanbing ( August 2021 , Inorganic Chemistry Frontiers)

   null (Ed.)

   Controlled energy transfer has been found to be one of the most effective ways of designing tunable and white photoluminescent phosphors. Utilizing host emission to achieve the same would lead to a new dimension in the design strategy for novel luminescent materials in solid state lighting and display devices. In this work, we have achieved controlled energy transfer by suppressing the host to dopant energy transfer in La 2 Hf 2 O 7 :Eu 3+ nanoparticles (NPs) by co-doping with uranium ions. Uranium acts as a barrier between the oxygen vacancies of the La 2 Hf 2 O 7 host and Eu 3+ doping ions to increase their separation and reduce the non-radiative energy transfer between them. Density functional theory (DFT) calculations of defect formation energy showed that the Eu 3+ dopant occupies the La 3+ site and the uranium ion occupies the Hf 4+ site. Co-doping the La 2 Hf 2 O 7 :Eu 3+ NPs with uranium ions creates negatively charged lanthanum and hafnium vacancies making the system highly electron rich. Formation of cation vacancies is expected to compensate the excess charge in the U and Eu co-doped La 2 Hf 2 O 7 NPs suppressing the formation of oxygen vacancies. This work shows how one can utilize the full color gamut in the La 2 Hf 2 O 7 :Eu 3+ ,U 6+ NPs with blue, green and red emissions from the host, uranium and europium, respectively, to produce near perfect white light emission. 

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3. Signatures of Non-universal Quantum Dynamics of Ultracold Chemical Reactions of Polar Alkali Dimer Molecules with Alkali Metal Atoms: Li( 2 S) + NaLi( a 3 Σ + ) → Na( 2 S) + Li 2 ( a 3 Σ u + )

   https://doi.org/10.1021/acs.jpclett.3c00159  

   Morita, Masato ; Kendrick, Brian K. ; Kłos, Jacek ; Kotochigova, Svetlana ; Brumer, Paul ; Tscherbul, Timur V. ( April 2023 , The Journal of Physical Chemistry Letters)
4. Quantum-vibrational-state-selected Integral Cross Sections and Product Branching Ratios for the Ion-molecule Reactions of N 2 + ( X 2 Σ g + ; v + = 0–2) + H 2 O and H 2 O + ( X 2 B 1 : v 1 + v 2 + v 3 + = 000 and 100) + N 2 in the Collision Energy Range of 0.04–10.00 eV

   https://doi.org/10.3847/1538-4357/aac9bf  

   Xu, Yuntao ; Xiong, Bo ; Chang, Yih Chung ; Ng, Cheuk-Yiu ( July 2018 , The Astrophysical Journal)
5. Organo‐Functionalized Lacunary Double Cubane‐Type Oxometallates: Synthesis, Structure, and Properties of [(M II Cl) 2 (V IV O) 2 {((HOCH 2 CH 2 )(H)N(CH 2 CH 2 O))(HN(CH 2 CH 2 O) 2 )} 2 ] (M=Co, Zn)

   https://doi.org/10.1002/chem.202301389  

   Shuaib, Damola T. ; Swenson, LaSalle ; Kaduk, James A. ; Chang, Tieyan ; Chen, Yu‐Sheng ; McNeely, James ; Khan, M. Ishaque ( October 2023 , Chemistry – A European Journal)

   Organofunctionalized tetranuclear clusters [(M^IICl)₂(V^IVO)₂{((HOCH₂CH₂)(H)N(CH₂CH₂O))(HN(CH₂CH₂O)₂)}₂] (1, M=Co,2: M=Zn) containing an unprecedented oxometallacyclic {M₂V₂Cl₂N₄O₈} (M=Co, Zn) framework have been prepared by solvothermal reactions. The new oxo‐alkoxide compounds were fully characterized by spectroscopic methods, magnetic susceptibility measurement, DFT and ab initio computational methods, and complete single‐crystal X‐ray diffraction structure analysis. The isostructural clusters are formed of edge‐sharing octahedral {VO₅N} and trigonal bipyramidal {MO₃NCl} units. Diethanolamine ligates the bimetallic lacunary double cubane core of1and2in an unusual two‐mode fashion, unobserved previously. In the crystalline state, the clusters of1and2are joined by hydrogen bonds to form a three‐dimensional network structure. Magnetic susceptibility data indicate weakly antiferromagnetic interactions between the vanadium centers [J_iso(V^IV−V^IV)=−5.4(1); −3.9(2) cm⁻¹], and inequivalent antiferromagnetic interactions between the cobalt and vanadium centers [J_iso(V^IV−Co^II)=−12.6 and −7.5 cm⁻¹] contained in1.

    

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