π‐Conjugated polymers have drawn broad interest in flexible electronics due to their solution processability, light weight, and a combination of conducting and light‐emitting properties. However, achieving mechanical endurance and stretchability in freestanding conjugated polymers is still difficult. Surface‐assembly‐induced light‐emitting polymer nanosheets with prodigious mechanical strength and charge transport are reported. Transferring freestanding polymer films onto various templates with conformal contact results in electrical and optical strain sensors with a gauge factor of ≈29. Subsequent geometric engineering into kirigami structures of the polymer sheets further extends the strain accommodations 20‐fold without compromising electric conductivity or fluorescence properties. These as‐prepared semiconducting polymers represent a possible new material for emerging stretchable electronics.
Constructing advanced functional nanomaterials with pre‐designed organized morphologies from low‐dimension synthetic and biological components is challenging. Herein, we report an efficient and universal amphiphilicity‐driven assembly strategy to construct “hairy” flexible hybrid nanosheets with a 1D cellulose nanofibers (CNFs) net conformally wrapped around 2D graphene oxide (GO) monolayers. This interface‐driven bio‐synthetic assembly is facilitated by tailoring the surface chemistry of flexible GO sheets, resulting in individual sheets tightly surrounded by dense conformal nanocellulose network. The mechanical stability of the products far exceeds the compressive instability limits of both individual components. Additionally, the CNF network significantly enhances the wetting ability of initial hydrophobic reduced GO nanosheets, allowing fast water transport combined with high filtration efficiency.
more » « less- NSF-PAR ID:
- 10063117
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Angewandte Chemie International Edition
- Volume:
- 57
- Issue:
- 28
- ISSN:
- 1433-7851
- Page Range / eLocation ID:
- p. 8508-8513
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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