This article reports a chain‐growth coupling polymerization of AB difunctional monomer via copper‐catalyzed azide–alkyne cycloaddition (CuAAC) reaction for synthesis of star polymers. Unlike our previously reported CuAAC polymerization of AB
The use of ionic liquids (ILs) as media in radical polymerizations has demonstrated the ability of these unique solvents to improve both reaction kinetics and polymer product properties. However, the bulk of these studies have examined the polymerization behavior of common organic monomers (e.g., methyl methacrylate, styrene) dissolved in conventional ILs. There is increasing interest in polymerized ILs (poly(ILs)), which are ionomers produced from the direct polymerization of styrene‐, vinyl‐, and acrylate‐functionalized ILs. Here, the photopolymerization kinetics of IL monomers are investigated for systems in which styrene or vinyl functionalities are pendant from the imidazolium cation. Styrene‐functionalized IL monomers typically polymerized rapidly (full conversion ≤1 min) in both neat compositions or when diluted with a nonpolymerizable IL, [C2mim][Tf2N]. However, monomer conversion in vinyl‐functionalized IL monomers is much more dependent on the nature of the nonpolymerizable group. ATR‐FTIR analysis and molecular simulations of these monomers and monomer mixtures identified the presence of multiple intermolecular interactions (e.g., π–π stacking, IL aggregation) that contribute to the polymerization behaviors of these systems. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem.
- PAR ID:
- 10074803
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Journal of Polymer Science Part A: Polymer Chemistry
- Volume:
- 56
- Issue:
- 20
- ISSN:
- 0887-624X
- Page Range / eLocation ID:
- p. 2364-2375
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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