An open‐to‐air method for the efficient synthesis of surface‐tethered polymer brushes based on photoinduced electron transfer‐reversible addition‐fragmentation chain transfer (PET‐RAFT) polymerization is reported. Key to this approach is an enzyme‐assisted strategy using glucose oxidase to facilitate the
Electrochemically mediated atom transfer radical polymerizations (ATRPs) provide well‐defined polymers with designed dispersity as well as under external temporal and spatial control. In this study, 1‐cyano‐1‐methylethyl diethyldithiocarbamate, typically used as chain‐transfer agent (CTA) in reversible addition–fragmentation chain transfer (RAFT) polymerization, was electrochemically activated by the ATRP catalyst CuI/2,2′‐bipyridine (bpy) to control the polymerization of methyl methacrylate. Mechanistic study showed that this polymerization was mainly controlled by the ATRP equilibrium. The effect of applied potential, catalyst counterion, catalyst concentration, and targeted degree of polymerization were investigated. The chain‐end functionality was preserved as demonstrated by chain extension of poly(methyl methacrylate) with
- Award ID(s):
- 1707490
- NSF-PAR ID:
- 10076406
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Journal of Polymer Science Part A: Polymer Chemistry
- Volume:
- 57
- Issue:
- 3
- ISSN:
- 0887-624X
- Page Range / eLocation ID:
- p. 376-381
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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