More Like this

1. Dynamics and Mechanisms of Mn(II), Co(II), Ni(II), Zn(II), and Cd(II) Sorption onto Green Rust Sulfate

   https://doi.org/10.1021/acs.est.3c01584  

   Alam, Khondaker_M N; Elzinga, Evert J (June 2023, Environmental Science & Technology)
2. Tetramethylcyclopentadienyl Samarium(II) Metallocene Chemistry: Isolation of a Bimetallic Sm(II)/Sm(II) Complex

   https://doi.org/10.3390/inorganics11010004  

   Nguyen, Joseph Q.; Ziller, Joseph W.; Evans, William J. (January 2023, Inorganics)

   The salt metathesis reaction between one equivalent of SmI2(THF)2 and two equivalents of K(C5Me4H) in THF afforded single crystals of the unusual, toluene-soluble, and asymmetric bimetallic Sm(II)/Sm(II) complex, (C5Me4H)2SmII(μ-η3:η5-C5Me4H)SmII(C5Me4H)(THF)2, instead of the expected product, (C5Me4H)2SmII(THF)2. The toluene-insoluble products of this reaction can be worked up in 1,2-dimethoxyethane (DME) to provide X-ray quality crystals of the monomeric Sm(II) metallocene, (C5Me4H)2SmII(DME). (C5Me4H)2SmII(DME) can also be synthesized directly by the reaction between one equivalent of SmI2(THF)2 and two equivalents of K(C5Me4H) in neat DME. The isolation and characterization of the bimetallic Sm(II)/Sm(II) complex provides supporting evidence for the possible oligomerization that may occur during the synthesis of Sm(II) complexes with cyclopentadienyl ligands that are less sterically bulky and less solubilizing than (C5Me5)1−. 

   more » « less
3. Observations on the Mechanochemical Insertion of Zinc(II), Copper(II), Magnesium(II), and Select Other Metal(II) Ions into Porphyrins

   https://doi.org/10.1021/acs.inorgchem.9b00052  

   Atoyebi, Adewole O.; Brückner, Christian (March 2019, Inorganic Chemistry)
4. Mononuclear Four-Coordinate Bis-Fluoride Bis-NHC Complexes of Chromium(II), Iron(II), and Cobalt(II)

   https://doi.org/10.1021/acs.inorgchem.3c02442  

   Acosta, Carlos M; Belov, Dmitry S; Lamur, Andy H; Brantley, ChristiAnna L; Solans-Monfort, Xavier; Rue, Kelly L; Christou, George; Bukhryakov, Konstantin V (November 2023, Inorganic Chemistry)
5. Explaining How α-Hydroxamate Ligands Control the Formation of Cu(II)-, Ni(II)-, and Zn(II)-Containing Metallacrowns

   https://doi.org/10.1021/acs.inorgchem.9b02724  

   Ostrowska, Malgorzata; Toporivska, Yuliya; Golenya, Irina A.; Shova, Sergiu; Fritsky, Igor O.; Pecoraro, Vincent L.; Gumienna-Kontecka, Elzbieta (November 2019, Inorganic Chemistry)