The sorption properties of [Zr 6 O 4 (OH) 4 (NH 3 + -BDC) 6 ]Cl 6 · x H 2 O ( MOR-1 ) and H 16 [Zr 6 O 16 (H 2 PATP) 4 ]Cl 8 · x H 2 O ( MOR-2 ) towards ReO 4 − and TcO 4 − were studied in detail. Both MOR-1 and MOR-2 are very effective sorbents for ReO 4 − and TcO 4 − anions, with MOR-2 showing the highest sorption capacity (up to 4.1 ± 0.4 mmol g −1 ) among the known metal organic materials. Importantly, the exceptional sorption capacity of MOR-2 is retained even under conditions simulating acidic nuclear waste. In addition, MOR-1 and MOR-2 exhibit selective luminescence ReO 4 − sensing properties, demonstrated for the first time for MOF materials.
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A soluble cyanide-bridged {Fe 4 Ni 4 } box encapsulating a Cs + ion: synthesis, structure and electronic properties
- Award ID(s):
- 1659782
- PAR ID:
- 10091480
- Date Published:
- Journal Name:
- Journal of Coordination Chemistry
- Volume:
- 71
- Issue:
- 5
- ISSN:
- 0095-8972
- Page Range / eLocation ID:
- 601 to 614
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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