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1. Dried, closed-path eddy covariance method for measuring carbon dioxide flux over sea ice

   https://doi.org/10.5194/amt-11-6075-2018  

   Butterworth, Brian J. ; Else, Brent G. ( January 2018 , Atmospheric Measurement Techniques)

   Abstract. The Arctic marine environment plays an important role inthe global carbon cycle. However, there remain large uncertainties in howsea ice affects air–sea fluxes of carbon dioxide (CO₂), partially dueto disagreement between the two main methods (enclosure and eddy covariance)for measuring CO₂ flux ($F_{\mathrm{CO}{}_{\mathrm{2}}}$). The enclosure method has appearedto produce more credible $F_{\mathrm{CO}{}_{\mathrm{2}}}$ than eddy covariance (EC), but is notsuited for collecting long-term, ecosystem-scale flux datasets in suchremote regions. Here we describe the design and performance of an EC systemto measure $F_{\mathrm{CO}{}_{\mathrm{2}}}$ over landfast sea ice that addresses the shortcomingsof previous EC systems. The system was installed on a 10m tower onQikirtaarjuk Island – a small rock outcrop in Dease Strait located roughly35km west of Cambridge Bay, Nunavut, in the Canadian Arctic Archipelago. Thesystem incorporates recent developments in the field of air–sea gasexchange by measuring atmospheric CO₂ using a closed-path infrared gasanalyzer (IRGA) with a dried sample airstream, thus avoiding the known watervapor issues associated with using open-path IRGAs in low-flux environments.A description of the methods and the results from 4 months of continuousflux measurements from May through August 2017 are presented, highlightingthe winter to summer transition from ice cover to open water. We show thatthe dried, closed-path EC system greatly reduces the magnitude of measured$F_{\mathrm{CO}{}_{\mathrm{2}}}$ compared to simultaneous open-path EC measurements, and for thefirst time reconciles EC and enclosure flux measurements over sea ice. Thisnovel EC installation is capable of operating year-round on solar and windpower, and therefore promises to deliver new insights into the magnitude ofCO₂ fluxes and their driving processes through the annual sea icecycle.

    

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2. Airborne and ground-based observations of ammonium-nitrate-dominated aerosols in a shallow boundary layer during intense winter pollution episodes in northern Utah

   https://doi.org/10.5194/acp-18-17259-2018  

   Franchin, Alessandro ; Fibiger, Dorothy L. ; Goldberger, Lexie ; McDuffie, Erin E. ; Moravek, Alexander ; Womack, Caroline C. ; Crosman, Erik T. ; Docherty, Kenneth S. ; Dube, William P. ; Hoch, Sebastian W. ; et al ( January 2018 , Atmospheric Chemistry and Physics)

   Abstract. Airborne and ground-based measurements of aerosol concentrations, chemicalcomposition, and gas-phase precursors were obtained in three valleys innorthern Utah (USA). The measurements were part of the Utah Winter FineParticulate Study (UWFPS) that took place in January–February 2017. Totalaerosol mass concentrations of PM₁ were measured from a Twin Otteraircraft, with an aerosol mass spectrometer (AMS). PM₁ concentrationsranged from less than 2µgm⁻³ during clean periods to over100µgm⁻³ during the most polluted episodes, consistent withPM_2.5 total mass concentrations measured concurrently at groundsites. Across the entire region, increases in total aerosol mass above∼2µgm⁻³ were associated with increases in theammonium nitrate mass fraction, clearly indicating that the highest aerosolmass loadings in the region were predominantly attributable to an increase inammonium nitrate. The chemical composition was regionally homogenous fortotal aerosol mass concentrations above 17.5µgm⁻³, with 74±5% (average±standard deviation) ammonium nitrate, 18±3%organic material, 6±3% ammonium sulfate, and 2±2%ammonium chloride. Vertical profiles of aerosol mass and volume in the regionshowed variable concentrations with height in the polluted boundary layer.Higher average mass concentrations were observed within the first few hundredmeters above ground level in all three valleys during pollution episodes. Gas-phase measurements of nitric acid (HNO₃) and ammonia (NH₃) duringthe pollution episodes revealed that in the Cache and Utah valleys, partitioningof inorganic semi-volatiles to the aerosol phase was usually limited by theamount of gas-phase nitric acid, with NH₃ being in excess. The inorganicspecies were compared with the ISORROPIA thermodynamic model. Total inorganicaerosol mass concentrations were calculated for various decreases in totalnitrate and total ammonium. For pollution episodes, our simulations of a50% decrease in total nitrate lead to a 46±3% decrease in totalPM₁ mass. A simulated 50% decrease in total ammonium leads to a36±17%µgm⁻³ decrease in total PM₁ mass, over the entirearea of the study. Despite some differences among locations, ourresults showed a higher sensitivity to decreasing nitric acid concentrationsand the importance of ammonia at the lowest total nitrate conditions. In theSalt Lake Valley, both HNO₃ and NH₃ concentrations controlledaerosol formation.

    

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3. Evaluating the timing and structure of the 4.2 ka event in the Indian summer monsoon domain from an annually resolved speleothem record from Northeast India

   https://doi.org/10.5194/cp-14-1869-2018  

   Kathayat, Gayatri ; Cheng, Hai ; Sinha, Ashish ; Berkelhammer, Max ; Zhang, Haiwei ; Duan, Pengzhen ; Li, Hanying ; Li, Xianglei ; Ning, Youfeng ; Edwards, R. Lawrence ( January 2018 , Climate of the Past)

   Abstract. A large array of proxy recordssuggests that the “4.2ka event” marks an approximately300-year long period (∼3.9 to 4.2ka) ofmajor climate change across the globe. However, the climatic manifestation ofthis event, including its onset, duration, and termination, remains lessclear in the Indian summer monsoon (ISM) domain. Here, we present new oxygenisotope (δ¹⁸O) data from a pair of speleothems (ML.1 and ML.2)from Mawmluh Cave, Meghalaya, India, that provide a high-resolution record ofISM variability during a period (∼3.78 and 4.44ka) that fullyencompasses the 4.2ka event. The sub-annually to annually resolved ML.1δ¹⁸O record is constrained by 18 ²³⁰Th dates with anaverage dating error of ±13 years (2σ) and a resolution of ∼40 years, which allows us to characterize the ISM variability withunprecedented detail. The inferred pattern of ISM variability during theperiod contemporaneous with the 4.2ka event shares broad similarities andkey differences with the previous reconstructions of ISM from the MawmluhCave and other proxy records from the region. Our data suggest that the ISMintensity, in the context of the length of our record, abruptly decreased at∼4.0ka ($\sim \pm \mathrm{13}$ years), marking the onset of a multi-centennialperiod of relatively reduced ISM, which was punctuated by at least twomulti-decadal droughts between ∼3.9 and 4.0ka. The latter stands outin contrast with some previous proxy reconstructions of the ISM, in which the4.2ka event has been depicted as a singular multi-centennial drought.

    

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4. Detecting the permafrost carbon feedback: talik formation and increased cold-season respiration as precursors to sink-to-source transitions

   https://doi.org/10.5194/tc-12-123-2018  

   Parazoo, Nicholas C. ; Koven, Charles D. ; Lawrence, David M. ; Romanovsky, Vladimir ; Miller, Charles E. ( January 2018 , The Cryosphere)

   Abstract. Thaw and release of permafrost carbon (C) due to climate change is likely tooffset increased vegetation C uptake in northern high-latitude (NHL)terrestrial ecosystems. Models project that this permafrost C feedback mayact as a slow leak, in which case detection and attribution of the feedbackmay be difficult. The formation of talik, a subsurface layer of perenniallythawed soil, can accelerate permafrost degradation and soil respiration,ultimately shifting the C balance of permafrost-affected ecosystems fromlong-term C sinks to long-term C sources. It is imperative to understand andcharacterize mechanistic links between talik, permafrost thaw, andrespiration of deep soil C to detect and quantify the permafrost C feedback.Here, we use the Community Land Model (CLM) version 4.5, a permafrost andbiogeochemistry model, in comparison to long-term deep borehole data alongNorth American and Siberian transects, to investigate thaw-driven C sourcesin NHL (>55^∘N) from 2000 to 2300. Widespread talik at depth isprojected across most of the NHL permafrost region(14million km²) by 2300, 6.2million km² of which isprojected to become a long-term C source, emitting 10Pg C by 2100,50Pg C by 2200, and 120Pg C by 2300, with few signs ofslowing. Roughly half of the projected C source region is in predominantlywarm sub-Arctic permafrost following talik onset. This region emits only20Pg C by 2300, but the CLM4.5 estimate may be biased low by notaccounting for deep C in yedoma. Accelerated decomposition of deep soilC following talik onset shifts the ecosystem C balance away from surfacedominant processes (photosynthesis and litter respiration), butsink-to-source transition dates are delayed by 20–200 years by highecosystem productivity, such that talik peaks early (∼2050s, although boreholedata suggest sooner) and C source transition peaks late(∼2150–2200). The remaining C source region in cold northern Arcticpermafrost, which shifts to a net source early (late 21st century), emits5 times more C (95Pg C) by 2300, and prior to talik formation dueto the high decomposition rates of shallow, young C in organic-rich soilscoupled with low productivity. Our results provide important clues signalingimminent talik onset and C source transition, including (1) late cold-season(January–February) soil warming at depth (∼2m),(2) increasing cold-season emissions (November–April), and (3) enhancedrespiration of deep, old C in warm permafrost and young, shallow C in organic-rich cold permafrost soils. Our results suggest a mosaic of processes thatgovern carbon source-to-sink transitions at high latitudes and emphasize theurgency of monitoring soil thermal profiles, organic C age and content, cold-season CO₂ emissions, andatmospheric ¹⁴CO₂ as key indicatorsof the permafrost C feedback.

    

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5. Physiological and biochemical responses of <i>Emiliania huxleyi</i> to ocean acidification and warming are modulated by UV radiation

   https://doi.org/10.5194/bg-16-561-2019  

   Tong, Shanying ; Hutchins, David A. ; Gao, Kunshan ( January 2019 , Biogeosciences)

   Abstract. Marine phytoplankton such as bloom-forming, calcite-producingcoccolithophores, are naturally exposed to solar ultraviolet radiation (UVR,280–400nm) in the ocean's upper mixed layers. Nevertheless, the effects ofincreasing carbon dioxide (CO₂)-induced ocean acidification and warming have rarelybeen investigated in the presence of UVR. We examined calcification andphotosynthetic carbon fixation performance in the most cosmopolitancoccolithophorid, Emiliania huxleyi, grown under high(1000µatm, HC; pH_T: 7.70) and low (400µatm,LC; pH_T: 8.02) CO₂ levels, at 15^∘C,20^∘C and 24^∘C with or without UVR. The HCtreatment did not affect photosynthetic carbon fixation at 15^∘C,but significantly enhanced it with increasing temperature. Exposure to UVRinhibited photosynthesis, with higher inhibition by UVA (320–395nm) thanUVB (295–320nm), except in the HC and 24^∘C-grown cells, in whichUVB caused more inhibition than UVA. A reduced thickness of the coccolith layerin the HC-grown cells appeared to be responsible for the UV-inducedinhibition, and an increased repair rate of UVA-derived damage in theHC–high-temperature grown cells could be responsible for lowered UVA-induced inhibition.While calcification was reduced with elevated CO₂ concentration,exposure to UVB or UVA affected the process differentially, with the formerinhibiting it and the latter enhancing it. UVA-induced stimulation of calcification washigher in the HC-grown cells at 15 and 20^∘C, whereas at24^∘C observed enhancement was not significant. The calcificationto photosynthesis ratio (Cal∕Pho ratio) was lower in the HC treatment,and increasing temperature also lowered the value. However, at 20 and24^∘C, exposure to UVR significantly increased the Cal∕Phoratio, especially in HC-grown cells, by up to 100%. This implies thatUVR can counteract the negative effects of the “greenhouse” treatment onthe Cal∕Pho ratio; hence, UVR may be a key stressor when considering theimpacts of future greenhouse conditions on E. huxleyi.

    

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