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Structurally elusive inositol hexakisphosphates have been trapped in host–guest sandwiches between two picolinamide macrocycles that remain intact in solution, aided by hydrogen bonds and electrostatic interactions. This first report of macrocyclic complexes of inositol hexakisphosphates provides structural insight to significant biosources of phosphorus that impact the global phosphorus cycle.
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Structural Impact of Chelation on Phytate, a Highly Phosphorylated Biomolecule: Structural Impact of Chelation on Phytate, a Highly Phosphorylated Biomolecule
- Award ID(s):
- 1710535
- PAR ID:
- 10095191
- Date Published:
- Journal Name:
- European Journal of Inorganic Chemistry
- Volume:
- 2019
- Issue:
- 14
- ISSN:
- 1434-1948
- Page Range / eLocation ID:
- 1870 to 1874
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1002/ejic.201900091
