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1. Structural discrimination from in situ measurement of ¹ D _CH and ² D _HH residual dipolar coupling constants: In situ measurement of ¹ D _CH and ² D _HH RDCs

   https://doi.org/10.1002/mrc.4575  

   Marcó, Núria ; Gil, Roberto R. ; Parella, Teodor ( June 2017 , Magnetic Resonance in Chemistry)
2. Fe ₄ Cluster and a Buckled Macrocycle Complex from the Reduction of [(dmgBF ₂ ) ₂ Fe(L) ₂ ] (L = MeCN, ^t Bu ⁱ NC)

   https://doi.org/10.1021/ic202253v  

   Rose, Michael J. ; Winkler, Jay R. ; Gray, Harry B. ( February 2012 , Inorganic Chemistry)
3. Molecular structure determination: Equilibrium structure of pyrimidine ( m -C ₄ H ₄ N ₂ ) from rotational spectroscopy ( r _e ^SE ) and high-level ab initio calculation ( r _e ) agree within the uncertainty of experimental measurement

   https://doi.org/10.1063/1.5144914  

   Heim, Zachary N. ; Amberger, Brent K. ; Esselman, Brian J. ; Stanton, John F. ; Woods, R. Claude ; McMahon, Robert J. ( March 2020 , The Journal of Chemical Physics)
4. White light emission from co-doped La ₂ Hf ₂ O ₇ nanoparticles with suppressed host → Eu ³⁺ energy transfer via a U ⁶⁺ co-dopant

   https://doi.org/10.1039/D1QI00134E  

   Gupta, Santosh K. ; Modak, Brindaban ; Modak, Pampa ; Mao, Yuanbing ( August 2021 , Inorganic Chemistry Frontiers)

   Controlled energy transfer has been found to be one of the most effective ways of designing tunable and white photoluminescent phosphors. Utilizing host emission to achieve the same would lead to a new dimension in the design strategy for novel luminescent materials in solid state lighting and display devices. In this work, we have achieved controlled energy transfer by suppressing the host to dopant energy transfer in La 2 Hf 2 O 7 :Eu 3+ nanoparticles (NPs) by co-doping with uranium ions. Uranium acts as a barrier between the oxygen vacancies of the La 2 Hf 2 O 7 host and Eu 3+ doping ions to increase their separation and reduce the non-radiative energy transfer between them. Density functional theory (DFT) calculations of defect formation energy showed that the Eu 3+ dopant occupies the La 3+ site and the uranium ion occupies the Hf 4+ site. Co-doping the La 2 Hf 2 O 7 :Eu 3+ NPs with uranium ions creates negatively charged lanthanum and hafnium vacancies making the system highly electron rich. Formation of cation vacancies is expected to compensate the excess charge in the U and Eu co-doped La 2 Hf 2 O 7 NPs suppressing the formationmore »of oxygen vacancies. This work shows how one can utilize the full color gamut in the La 2 Hf 2 O 7 :Eu 3+ ,U 6+ NPs with blue, green and red emissions from the host, uranium and europium, respectively, to produce near perfect white light emission.« less
5. Calcification of the planktonic foraminifera Globigerina bulloides and carbonate ion concentration: Results from the Santa Barbara Basin: Foram Calcification and [CO ₃ ^2? ]

   https://doi.org/10.1002/2016PA002933  

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