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1. Catalyzed baryogenesis

   https://doi.org/10.1007/JHEP10(2021)147  

   Bai, Yang; Berger, Joshua; Korwar, Mrunal; Orlofsky, Nicholas (October 2021, Journal of High Energy Physics)

   A bstract A novel mechanism, “catalyzed baryogenesis”, is proposed to explain the observed baryon asymmetry in our universe. In this mechanism, the motion of a ball-like catalyst provides the necessary out-of-equilibrium condition, its outer wall has CP-violating interactions with the Standard Model particles, and its interior has baryon number violating interactions. We use the electroweak-symmetric ball model as an example of such a catalyst. In this model, electroweak sphalerons inside the ball are active and convert baryons into leptons. The observed baryon number asymmetry can be produced for a light ball mass and a large ball radius. Due to direct detection constraints on relic balls, we consider a scenario in which the balls evaporate, leading to dark radiation at testable levels. 

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2. Nickel-Catalyzed Dicarbofunctionalization of Alkenes

   https://doi.org/10.1021/acscatal.0c02115  

   Qi, Xiaoxu; Diao, Tianning (August 2020, ACS Catalysis)

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3. Kinase-catalyzed biotinylation of DNA

   https://doi.org/10.1016/j.bmc.2018.03.027  

   Anthony, Thilani M.; Pflum, Mary Kay (May 2018, Bioorganic & Medicinal Chemistry)
4. Metal‐Catalyzed Hydrophosphination

   https://doi.org/10.1002/cctc.202200988  

   Novas, Bryan_T; Waterman, Rory (October 2022, ChemCatChem)

   Abstract Organophosphines have garnered attention from many avenues ranging from agriculture to fine chemicals. One‐time use of phosphate resources has made sustainable use of phosphorus overall imperative. Hydrophosphination serves as an efficient method to selectively prepare P−C bonds, furnishing a range of phosphorus‐containing molecules while maximizing the efficient use of phosphorus. Since the first report in 1958, a wide array of catalysts have appeared for hydrophosphination, a reaction that is spontaneous in some instances. This review presents a representative view of the literature based on known catalysts through mid‐2022, highlighting extensions to unique substrates and advances in selectivity. While several excellent reviews have appeared for aspects of this transformation, this review is meant as a comprehensive guide to reported catalysts. 

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5. Microgel-Catalyzed Hydrolysis of Nonactivated Disaccharides

   https://doi.org/10.1021/acscatal.0c03401  

   Striegler, Susanne; Sharma, Babloo; Orizu, Ifedi (December 2020, ACS Catalysis)

   null (Ed.)