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Title: [UF 6 ] 2− : A Molecular Hexafluorido Actinide(IV) Complex with Compensating Spin and Orbital Magnetic Moments
Abstract

The first structurally characterized hexafluorido complex of a tetravalent actinide ion, the [UF6]2−anion, is reported in the (NEt4)2[UF6]⋅2 H2O salt (1). The weak magnetic response of1results from both UIVspin and orbital contributions, as established by combining X‐ray magnetic circular dichroism (XMCD) spectroscopy and bulk magnetization measurements. The spin and orbital moments are virtually identical in magnitude, but opposite in sign, resulting in an almost perfect cancellation, which is corroborated by ab initio calculations. This work constitutes the first experimental demonstration of a seemingly non‐magnetic molecular actinide complex carrying sizable spin and orbital magnetic moments.

 
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Award ID(s):
1800252
NSF-PAR ID:
10116607
Author(s) / Creator(s):
 ;  ;  ;  ;  ;  ;  ;  ;  ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
Angewandte Chemie International Edition
Volume:
58
Issue:
44
ISSN:
1433-7851
Page Range / eLocation ID:
p. 15650-15654
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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