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1. A New Class of Molecular Electrocatalysts for Hydrogen Evolution: Catalytic Activity of M 3 N@C 2n (2 n = 68, 78, and 80) Fullerenes

   https://doi.org/10.1021/jacs.0c13002  

   Puente Santiago, Alain R. ; Sanad, Mohamed Fathi ; Moreno-Vicente, Antonio ; Ahsan, Md Ariful ; Cerón, Maira R. ; Yao, Yang-Rong ; Sreenivasan, Sreeprasad T. ; Rodriguez-Fortea, Antonio ; Poblet, Josep M. ; Echegoyen, Luis ( April 2021 , Journal of the American Chemical Society)

   null (Ed.)
2. Electronic structure calculation of vanadium‐and scandium‐based endohedral fullerenes VSc 2 N@C 2n (2 n = 70, 76, 78, 80)

   https://doi.org/10.1002/qua.25785  

   Bhusal, Shusil ; Baruah, Tunna ; Yamamoto, Yoh ; Zope, Rajendra R. ( September 2018 , International Journal of Quantum Chemistry)

   We present candidate structures for the most stable isomers for the VSc₂N@C₇₀, VSc₂N@C₇₆, VSc₂N@C₇₈, and VSc₂N@C₈₀using a systematic procedure that involves all possible isomers of the host fullerene cages. Subsequently, a detailed investigation of structural and electronic properties of the lowest energy isomers is performed using density functional theory in combination with large polarized Gaussian basis sets. The search correctly identifies the experimentally observed VSc₂N@C₈₀isomer as the most stable structure. The structural analysis shows that only VSc₂N@C₇₀has a non‐IPR cage among the four endohedral fullerenes. Respectively, VSc₂N@C₇₀and VSc₂N@C₇₆have nearly degenerate spin states with total spinS= 0 andS= 1. All the lowest energy cages are energetically stable and show significant electron accepting capacity comparable to C₆₀.

    

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3. “Click” Chemistry in Metal Coordination Spheres: Copper(I)-Catalyzed 3+2 Cycloadditions of Benzyl Azide and Platinum Polyynyl Complexes trans -(C 6 F 5 )( p -tol 3 P) 2 Pt(C≡C) n H ( n = 2−6)

   https://doi.org/10.1021/om900680q  

   Gauthier, Sébastien ; Weisbach, Nancy ; Bhuvanesh, Nattamai ; Gladysz, John A. ( October 2009 , Organometallics)
4. Reactions of Platinum Terminal Polyynyl Complexes trans -(C 6 F 5 )( p -tol 3 P) 2 Pt(C≡C) n H ( n = 2–4) and n -BuLi, Generation of Functional Equivalents of Pt(C≡C) n Li Species, and Derivatization with Organic and Inorganic Electrophiles

   https://doi.org/10.1021/acs.organomet.4c00098  

   Dey Baksi, Sourajit ; Aggrey, Joshua O. ; Bhuvanesh, Nattamai ; Gladysz, John A. ( April 2024 , Organometallics)
5. Millimeter/Submillimeter-wave Spectroscopy and the Semi-experimental Equilibrium ( r e SE ) Structure of 1 H -1,2,4-Triazole ( c -C 2 H 3 N 3 )

   https://doi.org/10.1021/acs.jpca.2c06038  

   Bunn, Hayley A. ; Esselman, Brian J. ; Franke, Peter R. ; Kougias, Samuel M. ; McMahon, Robert J. ; Stanton, John F. ; Widicus Weaver, Susanna L. ; Woods, R. Claude ( November 2022 , The Journal of Physical Chemistry A)