We present detections of [O iii] λ4363 and direct-method metallicities for star-forming galaxies at z = 1.7–3.6. We combine new measurements from the MOSFIRE Deep Evolution Field (MOSDEF) survey with literature sources to construct a sample of 18 galaxies with direct-method metallicities at z > 1, spanning 7.5 < 12+log(O/H) < 8.2 and log(M*/M⊙) = 7–10. We find that strong-line calibrations based on local analogues of high-redshift galaxies reliably reproduce the metallicity of the z > 1 sample on average. We construct the first mass–metallicity relation at z > 1 based purely on direct-method O/H, finding a slope that is consistent with strong-line results. Direct-method O/H evolves by ≲0.1 dex at fixed M* and star formation rate from z ∼ 0 to 2.2. We employ photoionization models to constrain the ionization parameter and ionizing spectrum in the high-redshift sample. Stellar models with supersolar O/Fe and binary evolution of massive stars are required to reproduce the observed strong-line ratios. We find that the z > 1 sample falls on the z ∼ 0 relation between ionization parameter and O/H, suggesting no evolution of this relation from z ∼ 0 to z ∼ 2. These results suggest that the offset of the strong-line ratios of this sample from local excitation sequences is driven primarily more »
- Publication Date:
- NSF-PAR ID:
- 10125576
- Journal Name:
- Monthly Notices of the Royal Astronomical Society
- Volume:
- 491
- Issue:
- 1
- Page Range or eLocation-ID:
- p. 1427-1455
- ISSN:
- 0035-8711
- Publisher:
- Oxford University Press
- Sponsoring Org:
- National Science Foundation
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