Flux Crystal Growth of Lanthanide Tungsten Oxychlorides, La 8.64 W 6 O 30.45 Cl, Ce 8.64 W 5.74 O 30 Cl, and Ln 8.33 W 6 O 30 Cl (Ln = Pr, Nd): Structural Stability in the Presence of Extreme Cation and Anion Disorder
- Award ID(s):
- 1806279
- PAR ID:
- 10140039
- Date Published:
- Journal Name:
- Inorganic Chemistry
- Volume:
- 58
- Issue:
- 24
- ISSN:
- 0020-1669
- Page Range / eLocation ID:
- 16831 to 16837
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
Abstract Heat capacities and enthalpies of formation of BaGd2O4were determined by high‐temperature differential scanning calorimetry and high‐temperature oxide melt solution calorimetry, respectively. Thermodynamic stability of BaLn2O4compounds increases with decreasing Ln3+ionic radius. Previously reported data on BaNd2O4and BaSm2O4corroborate this trend. Missing data for compounds in BaO–Ln2O3(Ln = La, Pr, Eu, Er) systems were estimated from established relations, thermodynamic assessment was performed, and binary phase diagrams were calculated.more » « less
An official website of the United States government

