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Title: Spectroscopic Description of the E 1 State of Mo Nitrogenase Based on Mo and Fe X-ray Absorption and Mössbauer Studies
Authors:
; ; ; ; ; ; ; ;
Award ID(s):
1654060
Publication Date:
NSF-PAR ID:
10142033
Journal Name:
Inorganic Chemistry
Volume:
58
Issue:
18
Page Range or eLocation-ID:
12365 to 12376
ISSN:
0020-1669
Sponsoring Org:
National Science Foundation
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  1. We present the synthesis, structure, and electrochemistry of K 3 [Mo 2 (SNO5) 4 Cl] 3 [Mo 2 (SNO5) 4 ] ( 1 , HSNO5 = monothiosuccinimide), the first example of a heterometallic extended metal atom node (HEMAN). The HEMAN consists of two perpendicular, intersecting lines of metal atoms formed by three [Mo 2 (SNO5) 4 Cl] − units and one [Mo 2 (SNO5) 4 ] unit tethered together by K + ions.