Spectroscopic Description of the E 1 State of Mo Nitrogenase Based on Mo and Fe X-ray Absorption and Mössbauer Studies
- Award ID(s):
- 1654060
- NSF-PAR ID:
- 10142033
- Date Published:
- Journal Name:
- Inorganic Chemistry
- Volume:
- 58
- Issue:
- 18
- ISSN:
- 0020-1669
- Page Range / eLocation ID:
- 12365 to 12376
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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We present the synthesis, structure, and electrochemistry of K 3 [Mo 2 (SNO5) 4 Cl] 3 [Mo 2 (SNO5) 4 ] ( 1 , HSNO5 = monothiosuccinimide), the first example of a heterometallic extended metal atom node (HEMAN). The HEMAN consists of two perpendicular, intersecting lines of metal atoms formed by three [Mo 2 (SNO5) 4 Cl] − units and one [Mo 2 (SNO5) 4 ] unit tethered together by K + ions.more » « less