In this study, silicon oxycarbide (SiOC) is selected as the base polymer to derive a SiOC ceramic (PDC) matrix, and four transition metals M (M = Ni, Mo, Co, and Zr) are individually introduced into the SiOC base to form various SiOC/M systems. SiOC‐Ni, SiOC‐MoC
In this study, novel ferromagnetic Ni‐containing silicon oxycarbide (SiOC–Ni) was successfully fabricated from a base polysiloxane (PSO) with the addition of nickel 2,4‐pentanedionate. The resultant SiOC–Ni nanocomposite consists of in situ formed Ni nanocrystallites with a small amount of NiO uniformly dispersed in the amorphous SiOC matrix, and the corresponding nanocrystallite size increases with the increase of the pyrolysis temperature. The formation of nickel silicides (Ni
- Award ID(s):
- 1634325
- NSF-PAR ID:
- 10447419
- Publisher / Repository:
- Wiley-Blackwell
- Date Published:
- Journal Name:
- Journal of the American Ceramic Society
- Volume:
- 103
- Issue:
- 1
- ISSN:
- 0002-7820
- Page Range / eLocation ID:
- p. 145-157
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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