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Title: Translocation of soft phytoglycogen nanoparticles through solid-state nanochannels
Phytoglycogen nanoparticles are soft, naturally-derived nanomaterials with a highly uniform size near 35 nm. Their interior is composed of a highly-branched polysaccharide core that contains more than 200% of its dry mass in water. In this work, we measure the translocation of phytoglycogen particles by observing blockade events they create when occluding solid-state nanochannels with diameters between 60 and 100 nm. The translocation signals are interpreted using Poisson–Nernst–Planck calculations with a “hardness parameter” that describes the extent to which solvent can penetrate through the interior of the particles. Theory and experiment were found to be in quantitative agreement, allowing us to extract physical characteristics of the particles on a per particle basis.  more » « less
Award ID(s):
1651002
PAR ID:
10147604
Author(s) / Creator(s):
; ; ;
Date Published:
Journal Name:
Journal of Materials Chemistry B
Volume:
7
Issue:
41
ISSN:
2050-750X
Page Range / eLocation ID:
6428 to 6437
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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