skip to main content


Title: Primitive Helium Is Sourced From Seismically Slow Regions in the Lowermost Mantle
Abstract

A major goal in Earth Science has been to understand how geochemical characteristics of lavas at the Earth's surface relate to the location and formation history of specific regions in the Earth's interior. For example, some of the strongest evidence for the preservation of primitive material comes from low4He/3He ratios in ocean island basalts, but the location of the primitive helium reservoir(s) remains unknown. Here we combine whole‐mantle seismic tomography, simulations of mantle flow, and a global compilation of new and existing measurements of the4He/3He ratios in ocean island basalts to constrain the source location of primitive4He/3He material. Our geodynamic simulations predict the present‐day surface expression of plumes to be laterally offset from their lower mantle source locations. When this lateral offset is accounted for, a strong relationship emerges between minimum4He/3He ratios in oceanic basalts and seismically slow regions, which are generally located within the two large low shear‐wave velocity provinces (LLSVPs). Conversely, no significant relationship is observed between maximum208Pb*/206Pb*ratios and seismically slow regions in the lowermost mantle. These results indicate that primitive materials are geographically restricted to LLSVPs, while recycled materials are more broadly distributed across the lower mantle. The primitive nature of the LLSVPs indicates these regions are not composed entirely of recycled slabs, while complementary xenon and tungsten isotopic anomalies require the primitive portion of the LLSVPs to have formed during Earth's accretion, survived the Moon‐forming giant impact, and remained relatively unmixed during the subsequent 4.5 billion years of mantle convection.

 
more » « less
Award ID(s):
1800324
NSF-PAR ID:
10458581
Author(s) / Creator(s):
 ;  ;  ;  
Publisher / Repository:
DOI PREFIX: 10.1029
Date Published:
Journal Name:
Geochemistry, Geophysics, Geosystems
Volume:
20
Issue:
8
ISSN:
1525-2027
Page Range / eLocation ID:
p. 4130-4145
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract

    Mantle plumes contain heterogenous chemical components and sample variable depths of the mantle, enabling glimpses into the compositional structure of Earth's interior. In this study, we evaluated ocean island basalts (OIB) from nine plume locations to provide a global and systematic assessment of the relationship betweenfO2and He‐Sr‐Nd‐Pb‐W‐Os isotopic compositions. Ocean island basalts from the Pacific (Austral Islands, Hawaii, Mangaia, Samoa, Pitcairn), Atlantic (Azores, Canary Islands, St. Helena), and Indian Oceans (La Réunion) reveal thatfO2in OIB is heterogeneous both within and among hotspots. Taken together with previous studies, global OIB have elevated and heterogenousfO2(average = +0.5 ∆FMQ; 2SD = 1.5) relative to prior estimates of global mid‐ocean ridge basalts (MORB; average = −0.1 ∆FMQ; 2SD = 0.6), though many individual OIB overlap MORB. Specific mantle components, such as HIMU and enriched mantle 2 (EM2), defined by radiogenic Pb and Sr isotopic compositions compared to other OIB, respectively, have distinctly highfO2based on statistical analysis. ElevatedfO2in OIB samples of these components is associated with higher whole‐rock CaO/Al2O3and olivine CaO content, which may be linked to recycled carbonated oceanic crust. EM1‐type and geochemically depleted OIB are generally not as oxidized, possibly due to limited oxidizing potential of the recycled material in the enriched mantle 1 (EM1) component (e.g., sediment) or lack of recycled materials in geochemically depleted OIB. Despite systematic offset of thefO2among EM1‐, EM2‐, and HIMU‐type OIB, geochemical indices of lithospheric recycling, such as Sr‐Nd‐Pb‐Os isotopic systems, generally do not correlate withfO2.

     
    more » « less
  2. null (Ed.)
    Oceanic island basalts are targeted for geochemical study because they provide a direct window into mantle composition and a wealth of information on the dynamics and timescales associated with Earth mixing. Previous studies mainly focused on the shield volcanic stage of oceanic islands and the more fusible, enriched mantle components that are easily distinguished in those basalts. Mantle depleted compositions are typically more difficult to resolve unless large amounts of this material participated in mantle melting (e.g., mid-ocean ridges), or unique processes allow for their compositions to be erupted undiluted, such as very small degrees of melting of a source with minimal fusible enriched components (e.g., rejuvenated basalts) or as xenoliths (e.g., abyssal peridotites). Mantle depleted components, defined here as material with low time-integrated Rb/Sr (low 87Sr/86Sr) and high time-integrated Sm/Nd and Lu/Hf ratios (high 143Nd/144Nd and 176Hf/177Hf) relative to primitive mantle, derive from a potentially very large volume reservoir (up to 80% of the mantle), and therefore need adequate characterization in order estimate the composition of the Earth and mantle-derived melts. This review focuses on mantle depleted compositions in oceanic island basalts using the Hawaiian-Emperor chain as a case study. The Hawaiian-Emperor chain is the ∼6000 km long geological record of the deeply sourced Hawaiian mantle plume, active for>81 Myr. Hawaiian volcanism evolves through four volcanic stages as a volcano traverses the Hawaiian plume: alkalic preshield, tholeiitic shield (80–90% volcano volume), alkalic postshield (∼1%), and silica undersaturated rejuvenated (< 0.1%). We report Pb-Sr-Nd-Hf isotope compositions and trace element concentrations of three rejuvenated Northwest Hawaiian Ridge basalts and compare them to an exhaustive compiled dataset of basalts from the Hawaiian Islands to the Emperor Seamounts. The Northwest Hawaiian Ridge (NWHR) includes 51 volcanoes spanning ∼42 m.y. between the bend in the Hawaiian-Emperor chain and the Hawaiian Islands where there is no high-precision isotopic data published on the rejuvenated-stage over ∼47% of the chain. NWHR and Hawaiian Island rejuvenated basalts are geochemically similar, indicating a consistent source for rejuvenated volcanism over ∼12.5 million years. In contrast, shield-stage basalts from the oldest Emperor Seamounts are more depleted in isotopic composition (i.e., higher 176Hf/177Hf, and 143Nd/144Nd with lower 87Sr/86Sr and 208Pb*/206Pb*) and trace element concentrations (i.e., much lower concentrations of highly incompatible elements) than all other depleted Hawaiian basalts younger than the bend, including NWHR rejuvenated basalts. The strongly depleted source for the oldest Emperor Seamounts (> 70 Ma) was likely related to interaction with the Kula-Pacific-Izanagi mid-ocean ridge spreading system active near the Hawaiian plume in the Late Cretaceous. In contrast, the incompatible trace element ratios of NWHR rejuvenated basalts require a distinct source in the Hawaiian mantle plume that was imprinted by ancient (> 1 Ga) partial melting, likely ancient recycled oceanic lithosphere. This review of the geochemistry of Hawaiian depleted components documents the need for the sampling of multiple distinctive depleted compositions, each preferentially melted during specific periods of Hawaiian plume activity. This suggests that the composition of depleted components can evolve during the lifetime of the mantle plume, as observed for enriched components in the Hawaiian mantle plume. Changes in the composition of depleted components are dominantly controlled by the upper mantle tectonic configurations at the time of eruption (i.e., proximity to a mid-ocean ridge), as this effect overwhelms the signal imparted by potentially sampling different lower mantle components through time. 
    more » « less
  3. Rare high-3He/4He signatures in ocean island basalts (OIB) erupted at volcanic hotspots derive from deep-seated domains preserved in Earth’s interior. Only high-3He/4He OIB exhibit anomalous182W—an isotopic signature inherited during the earliest history of Earth—supporting an ancient origin of high3He/4He. However, it is not understood why some OIB host anomalous182W while others do not. We provide geochemical data for the highest-3He/4He lavas from Iceland (up to 42.9 times atmospheric) with anomalous182W and examine how Sr-Nd-Hf-Pb isotopic variations—useful for tracing subducted, recycled crust—relate to high3He/4He and anomalous182W. These data, together with data on global OIB, show that the highest-3He/4He and the largest-magnitude182W anomalies are found only in geochemically depleted mantle domains—with high143Nd/144Nd and low206Pb/204Pb—lacking strong signatures of recycled materials. In contrast, OIB with the strongest signatures associated with recycled materials have low3He/4He and lack anomalous182W. These observations provide important clues regarding the survival of the ancient He and W signatures in Earth’s mantle. We show that high-3He/4He mantle domains with anomalous182W have low W and4He concentrations compared to recycled materials and are therefore highly susceptible to being overprinted with low3He/4He and normal (not anomalous)182W characteristic of subducted crust. Thus, high3He/4He and anomalous182W are preserved exclusively in mantle domains least modified by recycled crust. This model places the long-term preservation of ancient high3He/4He and anomalous182W in the geodynamic context of crustal subduction and recycling and informs on survival of other early-formed heterogeneities in Earth’s interior.

     
    more » « less
  4. Abstract

    There is a consensus that volcanism along the East African Rift System (EARS) is related to plume activities. However, because of our limited knowledge of the local lithospheric mantle, the dynamics of the plume are poorly constrained by magma chemistry. The Turkana Basin is one of the best places to study plume‐related volcanism because the lithospheric mantle there is unusually thin. New Ar‐Ar geochronology and geochemical data on lavas from western Turkana show that Eocene volcanics have relatively low206Pb/204Pb (<19.1) and high εNd (>3.78). Their relatively high Ba/Rb (35–78) ratios suggest contributions from the shallow lithospheric mantle. Oligo‐Miocene Turkana volcanics have HIMU‐ and EMI‐ type enriched mantle signatures with overall lower Ba/Rb ratios, which is consistent with partial melting of plume material. Pliocene and younger Turkana volcanics have low Ba/Rb and Sr‐Nd‐Pb isotope ratios that resemble those of Ethiopian volcanics with elevated3He/4He ratios. This temporal variation can be reconciled with a layered plume model where an outer layer of ancient recycled oceanic crust and sediment overlies more primitive lower mantle material. Beneath Ethiopia, the outer layer of the plume is either missing or punctured by the delamination of the thicker overlying lithospheric mantle atca.30 Ma, an event that would have facilitated the rapid upwelling of the inner portion of the plume and triggered the Ethiopian flood volcanism. The outer layer of the plume may be thicker in the southern EARS, which could explain the occurrence of young HIMU‐ and EMI‐type volcanics with primordial noble gas signatures.

     
    more » « less
  5. The hydrogen isotope value (δD) of water indigenous to the mantle is masked by the early degassing and recycling of surface water through Earth's history. High 3He/4He ratios in some ocean island basalts, however, provide a clear geochemical signature of deep, primordial mantle that has been isolated within the Earth's interior from melting, degassing, and convective mixing with the upper mantle. Hydrogen isotopes were measured in high 3He/4He submarine basalt glasses from the Southeast Indian Ridge (SEIR) at the Amsterdam–St. Paul (ASP) Plateau (δD = −51 to −90‰, 3He/4He = 7.6 to 14.1 RA) and in submarine glasses from Loihi seamount south of the island of Hawaii (δD = −70 to −90‰, 3He/4He = 22.5 to 27.8 RA). These results highlight two contrasting patterns of δD for high 3He/4He lavas: one trend toward high δD of approximately −50‰, and another converging at δD = −75‰. These same patterns are evident in a global compilation of previously reported δD and 3He/4He results. We suggest that the high δD values result from water recycled during subduction that is carried into the source region of mantle plumes at the core–mantle boundary where it is mixed with primordial mantle, resulting in high δD and moderately high 3He/4He. Conversely, lower δD values of −75‰, in basalts from Loihi seamount and also trace element depleted mid-ocean ridge basalts, imply a primordial Earth hydrogen isotopic value of −75‰ or lower. δD values down to −100‰ also occur in the most trace element-depleted mid-ocean ridge basalts, typically in association with 87Sr/86Sr ratios near 0.703. These lower δD values may be a result of multi-stage melting history of the upper mantle where minor D/H fractionation could be associated with hydrogen retention in nominally anhydrous residual minerals. Collectively, the predominance of δD around −75‰ in the majority of mid-ocean ridge basalts and in high 3He/4He Loihi basalts is consistent with an origin of water on Earth that was dominated by accretion of chondritic material. 
    more » « less