New Synthetic Route for Cobalt(III) Dissymmetric Bisalkynyl Complexes Based on Cobalt(III)(cyclam)(C 2 NAP Mes ): New Synthetic Route for Cobalt(III) Dissymmetric Bisalkynyl Complexes Based on Cobalt(III)(cyclam)(C 2 NAP Mes )
- Award ID(s):
- 1764347
- PAR ID:
- 10156310
- Date Published:
- Journal Name:
- European Journal of Inorganic Chemistry
- Volume:
- 2019
- Issue:
- 44
- ISSN:
- 1434-1948
- Page Range / eLocation ID:
- 4766 to 4772
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
Agostic interactions were observed in the bound mesityl group in a series of iron compounds bearing a bis(NHC) pincer CCC ligand. The L-type ligand on [(CCC)Fe II Mes(L)] complexes influences the strength of the agostic interaction and is manifested in the upfield shift of the 1 H NMR resonance for the mesityl methyl resonances. The nature of the interaction was further investigated by density functional theory calculations, allowing rationalization of some unexpected trends and proving to be a powerful predictive tool.more » « less
An official website of the United States government

