skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Evaluating ferrocene ions and all-ferrocene salts for electrochemical applications
Award ID(s):
1665267
PAR ID:
10157541
Author(s) / Creator(s):
; ; ;
Date Published:
Journal Name:
Journal of Organometallic Chemistry
Volume:
897
Issue:
C
ISSN:
0022-328X
Page Range / eLocation ID:
23 to 31
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. We show here that non-network metallopolymers can possess intrinsic microporosity stemming from contortion introduced by metallocene building blocks. Metallopolymers constructed from ferrocenyl building blocks linked by phenyldiacetylene bridges are synthesized and possess BET surface areas up to 400 m 2 g −1 . As solubility imparted by pendant groups reduces porosity, copolymerization is used to simultaneously improve both accessible surface area and solubility. Spectroscopic analysis provides evidence that mixed valency between neighboring ferrocenyl units is supported in these polymers. 
    more » « less