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1. Photophysics and Electronic Structure of Lateral Graphene/MoS 2 and Metal/MoS 2 Junctions

   https://doi.org/10.1021/acsnano.0c02527  

   Subramanian, Shruti ; Campbell, Quinn T. ; Moser, Simon K. ; Kiemle, Jonas ; Zimmermann, Philipp ; Seifert, Paul ; Sigger, Florian ; Sharma, Deeksha ; Al-Sadeg, Hala ; Labella, Michael ; et al ( December 2020 , ACS Nano)

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2. Intermixed WS 2 +MoS 2 Nanodisks/Graphene van der Waals Heterostructures for Surface-Enhanced Raman Spectroscopy Sensing

   https://doi.org/10.1021/acsanm.1c00087  

   Ghopry, Samar Ali ; Sadeghi, Seyed M. ; Farhat, Yasmine ; Berrie, Cindy L. ; Alamri, Mohammed ; Wu, Judy Z. ( March 2021 , ACS Applied Nano Materials)

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3. Extraordinary Sensitivity of Surface‐Enhanced Raman Spectroscopy of Molecules on MoS 2 (WS 2 ) Nanodomes/Graphene van der Waals Heterostructure Substrates

   https://doi.org/10.1002/adom.201801249  

   Ghopry, Samar A. ; Alamri, Mohammed A. ; Goul, Ryan ; Sakidja, Ridwan ; Wu, Judy Z. ( February 2019 , Advanced Optical Materials)

   Two‐dimensional transition metal dichalcogenides (TMDs)/graphene van der Waals (vdW) heterostructures integrate the superior light–solid interaction in TMDs and charge mobility in graphene, and therefore are promising for surface‐enhanced Raman spectroscopy (SERS). Herein, a novel TMD (MoS₂and WS₂) nanodome/graphene vdW heterostructure SERS substrate, on which an extraordinary SERS sensitivity is achieved, is reported. Using fluorescent Rhodamine 6G (R6G) as probe molecules, the SERS sensitivity is in the range of 10⁻¹¹to 10⁻¹²mon the TMD nanodomes/graphene vdW heterostructure substrates using 532 nm Raman excitation, which is comparable to the best sensitivity reported so far using plasmonic metal nanostructures/graphene SERS substrates, and is more than three orders of magnitude higher than that on single‐layer TMD and graphene substrates. Density functional theory simulation reveals enhanced electric dipole moments and dipole–dipole interaction at the TMD/graphene vdW interface, yielding an effective means to facilitate an external electrostatic perturbation on the graphene surface and charge transfer. This not only promotes chemical enhancement on SERS, but also enables electromagnetic enhancement of SERS through the excitation of localized surface plasmonic resonance on the TMD nanodomes. This TMD nanodome/graphene vdW heterostructure is therefore promising for commercial applications in high‐performance optoelectronics and sensing.

    

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4. Plasmonic Au Nanoparticles on 2D MoS 2 /Graphene van der Waals Heterostructures for High-Sensitivity Surface-Enhanced Raman Spectroscopy

   https://doi.org/10.1021/acsanm.8b02308  

   Alamri, Mohammed ; Sakidja, Ridwan ; Goul, Ryan ; Ghopry, Samar ; Wu, Judy Z. ( March 2019 , ACS Applied Nano Materials)
5. Tuning the defects in MoS 2 /reduced graphene oxide 2D hybrid materials for optimizing battery performance

   https://doi.org/10.1039/D1SE00729G  

   Muthukumar, Kamalambika ; Leban, Levon ; Sekar, Archana ; Elangovan, Ayyappan ; Sarkar, Nandini ; Li, Jun ( August 2021 , Sustainable Energy & Fuels)

   This study reports the preparation of a set of hybrid materials consisting of molybdenum disulfide (MoS 2 ) nanopatches on reduced graphene oxide (rGO) nanosheets by microwave specific heating of graphene oxide and molecular molybdenum precursors followed by thermal annealing in 3% H 2 and 97% Ar. The microwave process converts graphene oxide to ordered rGO nanosheets that are sandwiched between uniform thin layers of amorphous molybdenum trisulfide (MoS 3 ). The subsequent thermal annealing converts the intermediate layers into MoS 2 nanopatches with two-dimensional layered structures whose defect density is tunable by controlling the annealing temperature at 250, 325 and 600 °C, respectively. All three MoS 2 /rGO samples and the MoS 3 /rGO intermediate after the microwave step show a high Li-ion intercalation capacity in the initial 10 cycles (over 519 mA h g MoSx −1 , ∼3.1 Li + ions per MoS 2 ) which is attributed to the small MoS 2 nanopatches in the MoS 2 /rGO hybrids while the effect of further S-rich defects is insignificant. In contrast, the Zn-ion storage properties strongly depend on the defects in the MoS 2 nanopatches. The highly defective MoS 2 /rGO hybrid prepared by annealing at 250 °C shows the highest initial Zn-ion storage capacity (∼300 mA h g MoSx −1 ) and close to 100% coulombic efficiency, which is dominated by pseudocapacitive surface reactions at the edges or defects in the MoS 2 nanopatches. The fast fading in the initial cycles can be mitigated by applying higher charge/discharge currents or extended cycles. This study validates that defect engineering is critical for improving Zn-ion storage. 

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