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1. Toward Metal-Capped One-Dimensional Carbon Allotropes:  Wirelike C ₆ −C ₂₀ Polyynediyl Chains That Span Two Redox-Active (η ⁵ -C ₅ Me ₅ )Re(NO)(PPh ₃ ) Endgroups

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   Dembinski, Roman ; Bartik, Tamás ; Bartik, Berit ; Jaeger, Monika ; Gladysz, J. A. ( February 2000 , Journal of the American Chemical Society)
2. A New Route to Heterobimetallic C ₃ Complexes via C⋮C Metatheses of 1,3-Diynyl Ligands:  Synthesis and Structure of (η ⁵ -C ₅ Me ₅ )Re(NO)(PPh ₃ )(C⋮CC⋮)W(O- t -Bu) ₃

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   Dembinski, Roman ; Szafert, Slawomir ; Haquette, Pierre ; Lis, Tadeusz ; Gladysz, J. A. ( December 1999 , Organometallics)
3. Supramolecular Chemistry of Chiral Rhenium Lewis Acids of the Formula [ ( η ⁵ -C ₅ R ₅ )Re(NO)(CO)(PPh ₃ )] ⁺ :  Synthesis and Crystal Structure of a 2:1 Adduct of an Ammonia Complex and 18-Crown-6

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   Amoroso, Angelo J. ; Arif, Atta M. ; Gladysz, J. A. ( December 1997 , Organometallics)
4. Evaluating electrochemical accessibility of 4f ⁿ 5d ¹ and 4f ⁿ⁺¹ Ln( ii ) ions in (C ₅ H ₄ SiMe ₃ ) ₃ Ln and (C ₅ Me ₄ H) ₃ Ln complexes

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   The reduction potentials (reported vs. Fc + /Fc) for a series of Cp′ 3 Ln complexes (Cp′ = C 5 H 4 SiMe 3 , Ln = lanthanide) were determined via electrochemistry in THF with [ n Bu 4 N][BPh 4 ] as the supporting electrolyte. The Ln( iii )/Ln( ii ) reduction potentials for Ln = Eu, Yb, Sm, and Tm (−1.07 to −2.83 V) follow the expected trend for stability of 4f 7 , 4f 14 , 4f 6 , and 4f 13 Ln( ii ) ions, respectively. The reduction potentials for Ln = Pr, Nd, Gd, Tb, Dy, Ho, Er, and Lu, that form 4f n 5d 1 Ln( ii ) ions ( n = 2–14), fall in a narrow range of −2.95 V to −3.14 V. Only cathodic events were observed for La and Ce at −3.36 V and −3.43 V, respectively. The reduction potentials of the Ln( ii ) compounds [K(2.2.2-cryptand)][Cp′ 3 Ln] (Ln = Pr, Sm, Eu) match those of the Cp′ 3 Ln complexes. The reduction potentials of nine (C 5 Me 4 H) 3 Ln complexes were also studied and found to be 0.05–0.24 V more negative than those of the Cp′more »3 Ln compounds.« less
5. Synthesis and Reactivity of Functionalized Dimethylgermyl Complexes of the Formula (η ⁵ -C ₅ H ₅ )Re(NO)(PPh ₃ )(GeMe ₂ X); Equilibria Involving the Dimethylgermylene Complex [(η ⁵ -C ₅ H ₅ )Re(NO)(PPh ₃ )(=GeMe ₂ )]• TfO ⁻

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