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1. A New Class of Molecular Electrocatalysts for Hydrogen Evolution: Catalytic Activity of M ₃ N@C _2n (2 n = 68, 78, and 80) Fullerenes

   https://doi.org/10.1021/jacs.0c13002  

   Puente Santiago, Alain R.; Sanad, Mohamed Fathi; Moreno-Vicente, Antonio; Ahsan, Md Ariful; Cerón, Maira R.; Yao, Yang-Rong; Sreenivasan, Sreeprasad T.; Rodriguez-Fortea, Antonio; Poblet, Josep M.; Echegoyen, Luis (April 2021, Journal of the American Chemical Society)

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2. “Click” Chemistry in Metal Coordination Spheres: Copper(I)-Catalyzed 3+2 Cycloadditions of Benzyl Azide and Platinum Polyynyl Complexes trans -(C ₆ F ₅ )( p -tol ₃ P) ₂ Pt(C≡C) _n H ( n = 2−6)

   https://doi.org/10.1021/om900680q  

   Gauthier, Sébastien; Weisbach, Nancy; Bhuvanesh, Nattamai; Gladysz, John A. (October 2009, Organometallics)
3. Precise equilibrium structures of 1 H - and 2 H -1,2,3-triazoles (C ₂ H ₃ N ₃ ) by millimeter-wave spectroscopy

   https://doi.org/10.1063/5.0097750  

   Zdanovskaia, Maria A.; Esselman, Brian J.; Kougias, Samuel M.; Amberger, Brent K.; Stanton, John F.; Woods, R. Claude; McMahon, Robert J. (August 2022, The Journal of Chemical Physics)

   The 1 H- and 2 H-1,2,3-triazoles are isomeric five-membered ring, aromatic heterocycles that may undergo chemical equilibration by virtue of intramolecular hydrogen migration (tautomerization). Using millimeter-wave spectroscopy in the 130–375 GHz frequency range, we measured the spectroscopic constants for thirteen 1 H-1,2,3-triazole and sixteen 2 H-1,2,3-triazole isotopologues. Herein, we provide highly accurate and highly precise semi-experimental equilibrium ( r e SE ) structures for the two tautomers based on the spectroscopic constants of each set of isotopologues, together with vibration–rotation interaction and electron-mass distribution corrections calculated using coupled-cluster singles, doubles, and perturbative triples calculations [CCSD(T)/cc-pCVTZ]. The resultant structures are compared with a “best theoretical estimate” (BTE), which has recently been shown to be in exceptional agreement with the semi-experimental equilibrium structures of other aromatic molecules. Bond distances of the 1 H tautomer are determined to <0.0008 Å and bond angles to <0.2°. For the 2 H tautomer, bond angles are also determined to <0.2°, but bond distances are less precise (2σ ≤ 0.0015). Agreement between BTE and r e SE values is discussed. 

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4. Millimeter/Submillimeter-wave Spectroscopy and the Semi-experimental Equilibrium ( r _e ^SE ) Structure of 1 H -1,2,4-Triazole ( c -C ₂ H ₃ N ₃ )

   https://doi.org/10.1021/acs.jpca.2c06038  

   Bunn, Hayley A.; Esselman, Brian J.; Franke, Peter R.; Kougias, Samuel M.; McMahon, Robert J.; Stanton, John F.; Widicus Weaver, Susanna L.; Woods, R. Claude (November 2022, The Journal of Physical Chemistry A)
5. Synthesis, Reactivity, and Metal Complexes of Fluorous Triarylphosphines of the Formula P( p- C ₆ H ₄ (CH ₂ ) ₃ (CF ₂ ) _{n - 1} CF ₃ ) ₃ ( n = 6, 8, 10)

   https://doi.org/10.1021/om010193e  

   Soós, Tibor; Bennett, Byron L.; Rutherford, Drew; Barthel-Rosa, Luis P.; Gladysz, J. A. (July 2001, Organometallics)