- Award ID(s):
- 1833420
- NSF-PAR ID:
- 10168236
- Date Published:
- Journal Name:
- Reviews in mineralogy and geochemistry
- Volume:
- 86
- ISSN:
- 1943-2666
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Triple oxygen isotope (δ17O and δ18O) values of high- and low-temperature altered oceanic crust and products of basalt alteration experiments were measured to better constrain ocean isotope compositions in deep time. The data define an array of δ18O and Δ′17O (Δ′17O=δ′17O – λRL × δ′18O + γ) values from mantle values toward 1‰ and –0.01‰, respectively, with a λ of ~0.523. The altered oceanic crust data were used to construct a model for estimating δ18O-Δ′17O values of the ancient oceans if the continental weathering flux (FCW) and/or hydrothermal oceanic crust alteration flux (FHT) changed through time. A maximum lowering of 7‰ and 4‰, respectively, is achieved in the most extreme cases. The δ18O value of the ocean cannot be raised by more than 1.1‰. Eclogites from the Roberts Victor kimberlite (South Africa), with a protolith age of 3.1 Ga, have δ18O-Δ′17O values that precisely overlap with those of the modern altered oceanic crust, suggesting that the Archean oceans had similar isotope values as today. Published triple isotope data for Archean cherts show that all samples have been altered to some degree and suggest an Archean ocean surface temperature of ~70–100 °C. An ocean as light as –2‰ is still consistent with our eclogite data and reduce our temperature estimates by 10 °C.more » « less
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Granitic rocks, interpreted to be related to crustal melting, were emplaced into regions of thickened crust in southern Arizona during the Laramide orogeny (80–40 Ma). Laramide-age anatectic rocks are exposed as plutons, sills, and dike networks that are commonly found in the exhumed footwalls of metamorphic core complexes. This study investigates newly discovered exposures of granodioritic–leucogranitic rocks from three intrusive phases in the footwall of the Pinaleño–Jackson Mountain metamorphic core complex of southeastern Arizona, called the Relleno suite. Zircon U–Pb geochronology indicates that the suite was emplaced from 58 to 52 Ma. Zircon Lu/Hf isotope geochemistry, whole-rock Sr and Nd isotope geochemistry, and mineral O isotope geochemistry were used to investigate the source of these rocks and evaluate whether they are related to crustal anatexis. Average zircon εHf(t) values of the suite range from −4.7 to −7.9, whole-rock εNd(i) and 87Sr/86Sr(i) values range from −9.4 to −11.8 and 0.7064 to 0.7094 respectively, and quartz δ18OVSMOW values range from 6.8 to 9.4 ‰. Isotopic and geochemical data of these rocks are consistent with derivation from and assimilation of intermediate–mafic (meta)igneous rocks, at deep crustal levels, and are supported by thermodynamic melt models of Proterozoic igneous rocks equivalent to those exposed in the Pinaleño Mountains. In comparison with other Laramide-age anatectic granites in SE Arizona, those exposed in the Pinaleño Mountains are temporally similar but present compositional and isotopic differences that reflect melting and assimilation of different lithologies, producing distinct mineralogical and isotopic characteristics. The results suggest that crustal melting during this interval was not limited to metasedimentary protoliths and may have affected large portions of the deep crust. The early Paleogene Relleno suite in the Pinaleño Mountains strengthens the relationship between crustal melting and regions of thickened crust associated with the Sevier and Laramide orogenies.more » « less
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Abstract Abundant geologic evidence shows that atmospheric oxygen levels were negligible until the Great Oxidation Event (GOE) at 2.4–2.1 Ga. The burial of organic matter is balanced by the release of oxygen, and if the release rate exceeds efficient oxygen sinks, atmospheric oxygen can accumulate until limited by oxidative weathering. The organic burial rate relative to the total carbon burial rate can be inferred from the carbon isotope record in sedimentary carbonates and organic matter, which provides a proxy for the oxygen source flux through time. Because there are no large secular trends in the carbon isotope record over time, it is commonly assumed that the oxygen source flux changed only modestly. Therefore, declines in oxygen sinks have been used to explain the GOE. However, the average isotopic value of carbon fluxes into the atmosphere–ocean system can evolve due to changing proportions of weathering and outgassing inputs. If so, large secular changes in organic burial would be possible despite unchanging carbon isotope values in sedimentary rocks. Here, we present an inverse analysis using a self‐consistent carbon cycle model to determine the maximum change in organic burial since ~4 Ga allowed by the carbon isotope record and other geological proxies. We find that fractional organic burial may have increased by 2–5 times since the Archean. This happens because O2‐dependent continental weathering of13C‐depleted organics changes carbon isotope inputs to the atmosphere–ocean system. This increase in relative organic burial is consistent with an anoxic‐to‐oxic atmospheric transition around 2.4 Ga without declining oxygen sinks, although these likely contributed. Moreover, our inverse analysis suggests that the Archean absolute organic burial flux was comparable to modern, implying high organic burial efficiency and ruling out very low Archean primary productivity.
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Destabilization of Long‐Lived Hadean Protocrust and the Onset of Pervasive Hydrous Melting at 3.8 Ga
Abstract The nature of Earth's earliest crust and crustal processes remain unresolved questions in Precambrian geology. While some hypotheses suggest that plate tectonics began in the Hadean, others suggest that the Hadean was characterized by long‐lived protocrust and an absence of significant plate tectonic processes. Recently proposed trace‐element proxies for the tectono‐magmatic settings in which zircons formed are a relatively novel tool to understand crustal processes in the past. Here, we present high‐spatial resolution zircon trace and rare earth element geochemical data along with Hf and O isotope data of a new location with Hadean materials, 4.1–3.3 Ga detrital zircons from the 3.31 Ga Green Sandstone Bed, Barberton Greenstone Belt. Together, the hafnium isotope and trace element geochemistry of the detrital zircons record a major transition in crustal processes. Zircons older than 3.8 Ga show evidence for isolated, long‐lived protocrust derived by reworking of relatively undepleted mantle sources with limited remelting of surface‐altered material. After 3.8 Ga, Hf isotopic evidence for this protocrust is muted while relatively juvenile source components for the zircon's parental magmas and flux‐like melting signatures become more prominent. This shift mirrors changes in Hf isotopes and trace element geochemistry in other Archean terranes between ∼3.8 and 3.6 Ga and supports the notion that the global onset of pervasive crustal instability and recycling—A possible sign for mobile‐lid tectonics—Occurred in that time period.