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1. Effects of Oxygen Modification on the Structural and Magnetic Properties of Highly Epitaxial La0.7Sr0.3MnO3 (LSMO) thin films

   https://doi.org/10.1038/s41598-020-60343-5  

   Kumari, Shalini ; Mottaghi, Navid ; Huang, Chih-Yeh ; Trappen, Robbyn ; Bhandari, Ghadendra ; Yousefi, Saeed ; Cabrera, Guerau ; Seehra, Mohindar S. ; Holcomb, Mikel B. ( February 2020 , Scientific Reports)

   La_0.7Sr_0.3MnO₃, a strong semi-metallic ferromagnet having robust spin polarization and magnetic transition temperature (T_C) well above 300 K, has attracted significant attention as a possible candidate for a wide range of memory, spintronic, and multifunctional devices. Since varying the oxygen partial pressure during growth is likely to change the structural and other physical functionalities of La_0.7Sr_0.3MnO₃(LSMO) films, here we report detailed investigations on structure, along with magnetic behavior of LSMO films with same thickness (~30 nm) but synthesized at various oxygen partial pressures: 10, 30, 50, 100, 150, 200 and 250 mTorr. The observation of only (00 l) reflections without anymore »secondary peaks in the XRD patterns confirms the high-quality synthesis of the above-mentioned films. Surface morphology of the films reveals that these films are very smooth with low roughness, the thin films synthesized at 150 mTorr having the lowest average roughness. The increasing of magneticT_Cand sharpness of the magnetic phase transitions with increasing oxygen growth pressure suggests that by decreasing the oxygen growth pressure leads to oxygen deficiencies in grown films which induce oxygen inhomogeneity. Thin films grown at 150 mTorr exhibits the highest magnetization withT_C = 340 K as these thin films possess the lowest roughness and might exhibit lowest oxygen vacancies and defects. Interpretation and significance of these results in the 30 nm LSMO thin films prepared at different oxygen growth pressures are also presented, along with the existence and growth pressure dependence of negative remanent magnetization (NRM) of the above-mentioned thin films.

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2. Thermally Stimulated Depolarization Current Measurements on Degraded Lead Zirconate Titanate Films

   https://doi.org/10.1039/d1tc02668  

   Akkopru-Akgun, Betul ; Marincel, Daniel M. ; Tsuji, Kosuke ; Bayer, Thorsten J.M. ; Randall, Clive A. ; Lanagan, Michael T. ; and Trolier-McKinstry, Susan ( October 2021 , Journal of the American Ceramic Society)

   Charge transport mechanisms governing DC resistance degradation in ferroelectric films are influenced by defects, particularly oxygen vacancies. This paper demonstrates that oxygen vacancies migrate in lead zirconate titanate (PZT) films under a DC bias field and contribute to resistance degradation. Model PZT thin films were developed in which the concentration and distribution of oxygen vacancies were controlled via (a) changing the dopant type and concentration from 1%–4% Mn (acceptor) to 1%–4% Nb (donor) or (b) annealing undoped PZT films at varying partial pressures of PbO. The presence of associated (immobile) and dissociated (mobile) oxygen vacancies was distinguished by thermally stimulatedmore »depolarization current (TSDC) measurements. The impact of mobile oxygen vacancies on local defect chemistry and associated charge transport mechanisms was explored by electron energy loss spectroscopy (EELS). For Mn-doped PZT films, following resistance degradation, TSDC studies revealed only one depolarization peak with an activation energy of 0.6–0.8 eV; this peak was associated with ionic space charge presumably due to migration of oxygen vacancies. The magnitude of the depolarization current peak increased with increasing degradation times. A similar depolarization current peak attributed to the existence of mobile oxygen vacancies was also observed for undoped and Nb-doped PZT films; the magnitude of this peak decreased as the Nb or PbO contents in PZT films increased. An additional TSDC peak associated with polaron hopping between Ti3+ and Ti4+ was found in both Nb-doped PZT films and undoped PZT films annealed under low PbO partial pressure. Degraded Nb-doped samples exhibited a chemical shift in the TiL2,3 peak to lower energy losses and the appearance of shoulders on the t2g and eg peaks, implying a reduction of Ti cations in regions near the cathode.« less
3. Probing vacancy behavior across complex oxide heterointerfaces

   https://doi.org/10.1126/sciadv.aau8467  

   Zhu, Jiaxin ; Lee, Jung-Woo ; Lee, Hyungwoo ; Xie, Lin ; Pan, Xiaoqing ; De Souza, Roger A. ; Eom, Chang-Beom ; Nonnenmann, Stephen S. ( February 2019 , Science Advances)

   Oxygen vacancies ( V O • • ) play a critical role as defects in complex oxides in establishing functionality in systems including memristors, all-oxide electronics, and electrochemical cells that comprise metal-insulator-metal or complex oxide heterostructure configurations. Improving oxide-oxide interfaces necessitates a direct, spatial understanding of vacancy distributions that define electrochemically active regions. We show vacancies deplete over micrometer-level distances in Nb-doped SrTiO 3 (Nb:SrTiO 3 ) substrates due to deposition and post-annealing processes. We convert the surface potential across a strontium titanate/yttria-stabilized zirconia (STO/YSZ) heterostructured film to spatial (<100 nm) vacancy profiles within STO using ( T = 500°C)more »in situ scanning probes and semiconductor analysis. Oxygen scavenging occurring during pulsed laser deposition reduces Nb:STO substantially, which partially reoxidizes in an oxygen-rich environment upon cooling. These results (i) introduce the means to spatially resolve quantitative vacancy distributions across oxide films and (ii) indicate the mechanisms by which oxide thin films enhance and then deplete vacancies within the underlying substrate.« less
4. Local structure of Sr ₂ CuO _3.3 , a 95 K cuprate superconductor without CuO ₂ planes

   https://doi.org/10.1073/pnas.1918890117  

   Conradson, Steven D. ; Geballe, Theodore H. ; Jin, Changqing ; Cao, Lipeng ; Baldinozzi, Gianguido ; Jiang, Jack M. ; Latimer, Matthew J. ; Mueller, Oliver ( February 2020 , Proceedings of the National Academy of Sciences)

   The local structure of the highly “overdoped” 95 K superconductor Sr₂CuO_3.3determined by Cu K X-ray absorption fine structure (XAFS) at 62 K in magnetically oriented samples shows that 1) the magnetization is perpendicular to thecaxis; 2) at these levels of precision the Cu sublattice is tetragonal in agreement with the crystal structure; the O sublattice has 3) continuous -Cu-O- chains that orient perpendicular to an applied magnetic field; 4) approximately half-filled -Cu-O- chains that orient parallel to this field; 5) a substantial number of apical O vacancies; 6) O ions at some apical positions with expanded Cu-O distances; and 7)more »interstitial positions that imply highly displaced Sr ions. These results contradict the universally accepted features of cuprates that require intact CuO₂planes, magnetization along thecaxis, and a termination of the superconductivity when the excess charge on the CuO₂Cu ions exceeds 0.27. These radical differences in charge and structure demonstrate that this compound constitutes a separate class of Cu-O–based superconductors in which the superconductivity originates in a different, more complicated structural unit than CuO₂planes while retaining exceptionally high transition temperatures.

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5. A system for probing Casimir energy corrections to the condensation energy

   https://doi.org/10.1038/s41378-020-00221-2  

   Pérez-Morelo, Diego ; Stange, Alexander ; Lally, Richard W. ; Barrett, Lawrence K. ; Imboden, Matthias ; Som, Abhishek ; Campbell, David K. ; Aksyuk, Vladimir A. ; Bishop, David J. ( December 2020 , Microsystems & Nanoengineering)

   In this article, we present a nanoelectromechanical system (NEMS) designed to detect changes in the Casimir energy. The Casimir effect is a result of the appearance of quantum fluctuations in an electromagnetic vacuum. Previous experiments have used nano- or microscale parallel plate capacitors to detect the Casimir force by measuring the small attractive force these fluctuations exert between the two surfaces. In this new set of experiments, we aim to directly detect the shifts in the Casimir energy in a vacuum due to the presence of the metallic parallel plates, one of which is a superconductor. A change inmore »the Casimir energy of this configuration is predicted to shift the superconducting transition temperature (T_c) because of the interaction between it and the superconducting condensation energy. In our experiment, we take a superconducting film, carefully measure its transition temperature, bring a conducting plate close to the film, create a Casimir cavity, and then measure the transition temperature again. The expected shifts are smaller than the normal shifts one sees in cycling superconducting films to cryogenic temperatures, so using a NEMS resonator in situ is the only practical way to obtain accurate, reproducible data. Using a thin Pb film and opposing Au surface, we observe no shift inT_c>12 µK down to a minimum spacing of ~70 nm at zero applied magnetic field.

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