Slow Magnetic Relaxation in a Mononuclear Five-Coordinate Cu(II) Complex: Slow Magnetic Relaxation in a Mononuclear Five-Coordinate Cu(II) Complex
- Award ID(s):
- 1633870
- PAR ID:
- 10173644
- Date Published:
- Journal Name:
- European Journal of Inorganic Chemistry
- Volume:
- 2019
- Issue:
- 43
- ISSN:
- 1434-1948
- Page Range / eLocation ID:
- 4653 to 4659
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Three mononuclear six-coordinate Co( ii )-pseudohalide complexes [Co(L)X 2 ] with two N-donor pseudohalido coligands occupying the cis -positions (X = NCS − ( 1 ), NCSe − ( 2 ) or N(CN) 2 − ( 3 )), and a five-coordinate complex [Co(L)(NCO)][B(C 6 H 5 ) 4 ] ( 4 ) [L = 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane (12-TMC)] have been prepared and structurally characterized. Easy-plane magnetic anisotropy for 1–3 and easy-axis anisotropy for 4 were revealed via the analyses of the direct-current magnetic data, high-frequency and -field EPR (HFEPR) spectra and ab initio theoretical calculations. They display slow magnetic relaxations under an external applied dc field. Typically, two slow relaxation processes were found in 1 and 2 while only one relaxation process occurs in 3 and 4 . The Raman-like mechanism is found to be dominant in the studied temperature range in 1 . For 2–4 , the Raman process is dominant in the low temperature region, while the Orbach mechanism dominates in the high temperature range.more » « less
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