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1. K 3 [Mo 2 (SNO5) 4 Cl] 3 [Mo 2 (SNO5) 4 ]: the first example of a heterometallic extended metal atom node (HEMAN)

   https://doi.org/10.1039/c6dt03659g  

   Dolinar, Brian S. ; Kozimor, Stosh A. ; Berry, John F. ( January 2016 , Dalton Transactions)

   We present the synthesis, structure, and electrochemistry of K 3 [Mo 2 (SNO5) 4 Cl] 3 [Mo 2 (SNO5) 4 ] ( 1 , HSNO5 = monothiosuccinimide), the first example of a heterometallic extended metal atom node (HEMAN). The HEMAN consists of two perpendicular, intersecting lines of metal atoms formed by three [Mo 2 (SNO5) 4 Cl] − units and one [Mo 2 (SNO5) 4 ] unit tethered together by K + ions. 

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2. The Prototypical Transition Metal Carbenes, (CO) 5 Cr=CH 2 , (CO) 4 Fe=CH 2 , (CO) 3 Ni=CH 2 , (CO) 5 Mo=CH 2 , (CO) 4 Ru=CH 2 , (CO) 3 Pd=CH 2 , (CO) 5 W=CH 2 , (CO) 4 Os=CH 2 , and (CO) 3 Pt=CH 2 : Challenge to Experiment

   https://doi.org/10.1021/acs.jpca.8b05394  

   Weidman, Jared D. ; Estep, Marissa L. ; Schaefer, Henry F. ( July 2018 , The Journal of Physical Chemistry A)
3. Removal of CrO 4 2– , a Nonradioactive Surrogate of 99 TcO 4 – , Using LDH–Mo 3 S 13 Nanosheets

   https://doi.org/10.1021/acs.est.1c08766  

   Celik, Ahmet ; Li, Dien ; Quintero, Michael A. ; Taylor-Pashow, Kathryn M. ; Zhu, Xianchun ; Shakouri, Mohsen ; Roy, Subrata Chandra ; Kanatzidis, Mercouri G. ; Arslan, Zikri ; Blanton, Alicia ; et al ( June 2022 , Environmental Science & Technology)
4. Correlating magnetic anisotropy with [Mo(CN) 7 ] 4− geometry of Mn II –Mo III magnetic frameworks

   https://doi.org/10.1039/c9dt02164g  

   Magott, Michał ; Dunbar, Kim R. ; Pinkowicz, Dawid ( January 2019 , Dalton Transactions)

   Four new three-dimensional (3-D) coordination frameworks based on the heptacyanomolybdate( iii ) anion were prepared and characterised by magnetic measurements: {[Mn II (imH) 2 ] 2 [Mn II (H 2 O)(imH) 3 ][Mn II (imH) 4 ] [Mo III (CN) 7 ] 2 ·6H 2 O} n ( 1 ) (imH = imidazole), {[Mn II (H 2 O) 2 (imH)] 3 [Mn II (H 2 O)(imH) 2 ][Mo III (CN) 7 ] 2 ·5H 2 O} n ( 2 ), {[Mn II (Htrz)(H 2 O) 2 ][Mn II (Htrz) 0.7 (H 2 O) 2.3 ][Mo III (CN) 7 ]·5.6H 2 O} n ( 3 ) (Htrz = 1,2,4-triazole) and {[Mn II (H 2 O) 2 ] 3 [Mn II (H 2 O) 4 ][Mo III (CN) 7 ] 2 ·6H 2 O·2urea} n ( 4 ). All four compounds exhibit long-range ferrimagnetic ordering and exhibit an opening of their magnetic hysteresis loops at 1.8 K; 1 and 2 exhibit the highest coercive fields among all known [Mo III (CN) 7 ]-based assemblies, 5000 and 4500 Oe respectively. The coercivity of 1–4 is correlated with the geometry of the heptacyanomolybdate( iii ) anion and the cyanide bridging pattern. A paramagnetic analogue of compound 1 , {[Mn II (imH) 2 ] 2 [Mn II (H 2 O)(imH) 3 ][Mn II (imH) 4 ][Re III (CN) 7 ] 2 ·6H 2 O} n ( 1Re ), where the heptacyanomolybdate( iii ) anion is substituted by the diamagnetic heptacyanorhenate( iii ) anion is also reported which constitutes the first example of a coordination framework based on [Re III (CN) 7 ] 4− . 

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5. Conversion of Single Crystal (NH 4 ) 2 Mo 3 S 13 ·H 2 O to Isomorphic Pseudocrystals of MoS 2 Nanoparticles

   https://doi.org/10.1021/acs.chemmater.8b01247  

   Islam, Saiful M. ; Cain, Jeffrey D. ; Shi, Fengyuan ; He, Yihui ; Peng, Lintao ; Banerjee, Abhishek ; Subrahmanyam, Kota S. ; Li, Yuan ; Ma, Shulan ; Dravid, Vinayak P. ; et al ( May 2018 , Chemistry of Materials)