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1. Mixed-carbene cyclometalated iridium complexes with saturated blue luminescence

   https://doi.org/10.1039/C9SC01386E  

   Na, Hanah; Cañada, Louise M.; Wen, Zhili; I-Chia Wu, Judy; Teets, Thomas S. (June 2019, Chemical Science)

   Cyclometalated iridium complexes have emerged as top-performing emitters in organic light-emitting diodes (OLEDs) and other optoelectronic devices. A persistent challenge has been the development of cyclometalated iridium complexes with deep blue luminescence that have the requisite color purity, efficiency, and stability to function in color displays. In this work we report a new class of cyclometalated iridium complexes with saturated blue luminescence. These complexes have the general structure Ir(C^C: NHC ) 2 (C^C: ADC ), where C^C: NHC is an N-heterocyclic carbene (NHC) derived cyclometalating ligand and C^C: ADC is a different type of cyclometalating ligand featuring an acyclic diaminocarbene (ADC). The complexes are prepared by a cascade reaction that involves nucleophilic addition of propylamine to an isocyanide precursor followed by base-assisted cyclometalation of the ADC intermediate. All three emit deep blue light with good quantum efficiencies ( Φ PL = 0.13–0.48) and color profiles very close to the ideal primary blue standards for color displays. 

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2. Blue-phosphorescent bis-cyclometalated iridium complexes with aryl isocyanide ancillary ligands

   https://doi.org/10.1016/j.poly.2019.114332  

   Cañada, Louise M.; Kölling, Johanna; Teets, Thomas S. (March 2020, Polyhedron)
3. Enhanced Deep-Red Phosphorescence in Cyclometalated Iridium Complexes with Quinoline-Based Ancillary Ligands

   https://doi.org/10.1021/acs.inorgchem.3c00670  

   Yoon, Sungwon; Gray, Thomas G.; Teets, Thomas S. (May 2023, Inorganic Chemistry)
4. Manipulating Excited State Properties of Iridium Phenylpyridine Complexes with “Push–Pull” Substituents

   https://doi.org/10.1021/acs.inorgchem.2c02269  

   Turner, Emigdio E.; Breen, Douglas J.; Kosgei, Gilbert; Crandall, Laura A.; Curtin, Gregory M.; Jakubikova, Elena; O’Donnell, Ryan M.; Ziegler, Christopher J.; Rack, Jeffrey J. (November 2022, Inorganic Chemistry)
5. Modular Imine Chelates with Variable Anionic Donors Promote Red Phosphorescence in Cyclometalated Iridium Complexes

   https://doi.org/10.1021/acs.inorgchem.3c01770  

   Jiang, Chenggang; Yoon, Sungwon; Nguyen, Yennie H.; Teets, Thomas S. (July 2023, Inorganic Chemistry)