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Title: Formation of stable aggregates by fluid-assembled solid bridges
When a colloidal suspension is dried, capillary pressure may overwhelm repulsive electrostatic forces, assembling aggregates that are out of thermal equilibrium. This poorly understood process confers cohesive strength to many geological and industrial materials. Here we observe evaporation-driven aggregation of natural and synthesized particulates, probe their stability under rewetting, and measure bonding strength using an atomic force microscope. Cohesion arises at a common length scale (∼5 μm), where interparticle attractive forces exceed particle weight. In polydisperse mixtures, smaller particles condense within shrinking capillary bridges to build stabilizing “solid bridges” among larger grains. This dynamic repeats across scales, forming remarkably strong, hierarchical clusters, whose cohesion derives from grain size rather than mineralogy. These results may help toward understanding the strength and erodibility of natural soils, and other polydisperse particulates that experience transient hydrodynamic forces.  more » « less
Award ID(s):
1833478
PAR ID:
10182344
Author(s) / Creator(s):
; ; ;
Date Published:
Journal Name:
Proceedings of the National Academy of Sciences
Volume:
117
Issue:
7
ISSN:
0027-8424
Page Range / eLocation ID:
3375 to 3381
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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