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1. Changing inputs of continental and submarine weathering sources of Sr to the oceans during OAE 2

   https://doi.org/10.46427/gold2020.1889  

   Nana Yobo, L. ; Brandon, A.D. ; Holmden, C. ; Lau, K.V. ; Eldrett, J. ( June 2021 , Geochimica et cosmochimica acta)

   Jacobson, A. (Ed.)

   Ocean anoxic events (OAE) are characterized by increased organic content of marine sediment on a global scale with accompanying positive excursions in sedimentary organic and inorganic d 13C values. To sustain the increased C exports and burial required to explain the C isotope excursion, increased supplies of nutrients to the oceans are often invoked during ocean anoxic events. The potential source of nutrients in these events is investigated in this study for Oceanic Anoxic Event 2, which spans the Cenomanian-Turonian boundary. Massive eruptions of one or more Large Igneous Provinces (LIPs) are the proposed trigger for OAE 2. The global warming associated with volcanogenic loading of carbon dioxide to the atmosphere has been associated with increased continental weathering rates during OAE 2, and by extension, enhanced nutrient supplies to the oceans. Seawater interactions with hot basalts at LIP eruption sites can further deliver ferrous iron and other reduced metals to seawater that can stimulate increased productivity in surface waters and increased oxygen demand in deep waters. The relative importance of continental and submarine weathering drivers of expanding ocean anoxia during OAE 2 are difficult to disentangle. In this paper, a box model of the marine Sr cycle is used to constrain the timing and relative magnitudes of changes in the continental weathering and hydrothermal Sr fluxes to the oceans during OAE 2 using a new high-resolution record of seawater 87Sr/86Sr ratios preserved in a marl-limestone succession from the Iona-1 core collected from the Eagle Ford Formation in Texas. The results show that seawater 87Sr/86Sr ratios change synchronously with Os isotope evidence for the onset of massive LIP volcanism 60 kyr before the positive C isotope excursion that traditionally marks the onset of OAE 2. The higher temporal resolution of the seawater Sr isotope record presented in this study warrants a detailed quantitative analysis of the changes in continental weathering and hydrothermal Sr inputs to the oceans during OAE 2. Using an ocean Sr box model, it is found that increasing the continental weathering Sr flux by  1.8-times captures the change in seawater 87Sr/86Sr recorded in the Iona-1 core. The increase in the continental weathering flux is smaller than the threefold increase estimated by studies of seawater Ca isotope changes during OAE 2, suggesting that hydrothermal forcing may have played a larger role in the development of ocean anoxic events than previously considered. 

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2. Changing inputs of continental and submarine weathering sources of Sr to the oceans during OAE2

   https://doi.org/doi.org/10.1016/gca.2021.03.013  

   Nana Yobo, L. ; Brandon, A.D. ; Holmden, C. ; Lau, K.V. ; Eldrett, J. ( January 2022 , Geochimica et cosmochimica acta)

   Jacobson, A. (Ed.)

   Ocean anoxic events (OAE) are characterized by increased organic content of marine sediment on a global scale with accompanying positive excursions in sedimentary organic and inorganic d 13C values. To sustain the increased C exports and burial required to explain the C isotope excursion, increased supplies of nutrients to the oceans are often invoked during ocean anoxic events. The potential source of nutrients in these events is investigated in this study for Oceanic Anoxic Event 2, which spans the Cenomanian-Turonian boundary. Massive eruptions of one or more Large Igneous Provinces (LIPs) are the proposed trigger for OAE 2. The global warming associated with volcanogenic loading of carbon dioxide to the atmosphere has been associated with increased continental weathering rates during OAE 2, and by extension, enhanced nutrient supplies to the oceans. Seawater interactions with hot basalts at LIP eruption sites can further deliver ferrous iron and other reduced metals to seawater that can stimulate increased productivity in surface waters and increased oxygen demand in deep waters. The relative importance of continental and submarine weathering drivers of expanding ocean anoxia during OAE 2 are difficult to disentangle. In this paper, a box model of the marine Sr cycle is used to constrain the timing and relative magnitudes of changes in the continental weathering and hydrothermal Sr fluxes to the oceans during OAE 2 using a new high-resolution record of seawater 87Sr/86Sr ratios preserved in a marl-limestone succession from the Iona-1 core collected from the Eagle Ford Formation in Texas. The results show that seawater 87Sr/86Sr ratios change synchronously with Os isotope evidence for the onset of massive LIP volcanism 60 kyr before the positive C isotope excursion that traditionally marks the onset of OAE 2. The higher temporal resolution of the seawater Sr isotope record presented in this study warrants a detailed quantitative analysis of the changes in continental weathering and hydrothermal Sr inputs to the oceans during OAE 2. Using an ocean Sr box model, it is found that increasing the continental weathering Sr flux by
   1.8-times captures the change in seawater 87Sr/86Sr recorded in the Iona-1 core. The increase in the continental weathering flux is smaller than the threefold increase estimated by studies of seawater Ca isotope changes during OAE 2, suggesting that hydrothermal forcing may have played a larger role in the development of ocean anoxic events than previously considered. 

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3. Carbon cycle inverse modeling suggests large changes in fractional organic burial are consistent with the carbon isotope record and may have contributed to the rise of oxygen

   https://doi.org/10.1111/gbi.12440  

   Krissansen‐Totton, Joshua ; Kipp, Michael A. ; Catling, David C. ( March 2021 , Geobiology)

   Abundant geologic evidence shows that atmospheric oxygen levels were negligible until the Great Oxidation Event (GOE) at 2.4–2.1 Ga. The burial of organic matter is balanced by the release of oxygen, and if the release rate exceeds efficient oxygen sinks, atmospheric oxygen can accumulate until limited by oxidative weathering. The organic burial rate relative to the total carbon burial rate can be inferred from the carbon isotope record in sedimentary carbonates and organic matter, which provides a proxy for the oxygen source flux through time. Because there are no large secular trends in the carbon isotope record over time, it is commonly assumed that the oxygen source flux changed only modestly. Therefore, declines in oxygen sinks have been used to explain the GOE. However, the average isotopic value of carbon fluxes into the atmosphere–ocean system can evolve due to changing proportions of weathering and outgassing inputs. If so, large secular changes in organic burial would be possible despite unchanging carbon isotope values in sedimentary rocks. Here, we present an inverse analysis using a self‐consistent carbon cycle model to determine the maximum change in organic burial since ~4 Ga allowed by the carbon isotope record and other geological proxies. We find that fractional organic burial may have increased by 2–5 times since the Archean. This happens because O₂‐dependent continental weathering of¹³C‐depleted organics changes carbon isotope inputs to the atmosphere–ocean system. This increase in relative organic burial is consistent with an anoxic‐to‐oxic atmospheric transition around 2.4 Ga without declining oxygen sinks, although these likely contributed. Moreover, our inverse analysis suggests that the Archean absolute organic burial flux was comparable to modern, implying high organic burial efficiency and ruling out very low Archean primary productivity.

    

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4. Molecular and isotopic evidence reveals the end-Triassic carbon isotope excursion is not from massive exogenous light carbon

   https://doi.org/10.1073/pnas.1917661117  

   Fox, Calum P. ; Cui, Xingqian ; Whiteside, Jessica H. ; Olsen, Paul E. ; Summons, Roger E. ; Grice, Kliti ( November 2020 , Proceedings of the National Academy of Sciences)

   The negative organic carbon isotope excursion (CIE) associated with the end-Triassic mass extinction (ETE) is conventionally interpreted as the result of a massive flux of isotopically light carbon from exogenous sources into the atmosphere (e.g., thermogenic methane and/or methane clathrate dissociation linked to the Central Atlantic Magmatic Province [CAMP]). Instead, we demonstrate that at its type locality in the Bristol Channel Basin (UK), the CIE was caused by a marine to nonmarine transition resulting from an abrupt relative sea level drop. Our biomarker and compound-specific carbon isotopic data show that the emergence of microbial mats, influenced by an influx of fresh to brackish water, provided isotopically light carbon to both organic and inorganic carbon pools in centimeter-scale water depths, leading to the negative CIE. Thus, the iconic CIE and the disappearance of marine biota at the type locality are the result of local environmental change and do not mark either the global extinction event or input of exogenous light carbon into the atmosphere. Instead, the main extinction phase occurs slightly later in marine strata, where it is coeval with terrestrial extinctions and ocean acidification driven by CAMP-induced increases inPco₂; these effects should not be conflated with the CIE. An abrupt sea-level fall observed in the Central European basins reflects the tectonic consequences of the initial CAMP emplacement, with broad implications for all extinction events related to large igneous provinces.

    

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5. Paleoproterozoic Plate Tectonics Recorded in the Northern Margin Orogen, North China Craton

   https://doi.org/10.1029/2022GC010662  

   Wu, Chen ; Wang, Guosheng ; Zhou, Zhiguang ; Haproff, Peter J. ; Zuza, Andrew V. ; Liu, Wenyou ( November 2022 , Geochemistry, Geophysics, Geosystems)

   The occurrence of plate tectonic processes on Earth during the Paleoproterozoic is supported by ca. 2.2–1.8 Ga subduction‐collision orogens associated with the assembly of the Columbia‐Nuna supercontinent. Subsequent supercontinent breakup is evidence by global ca. 1.8–1.6 Ga large igneous provinces. The North China craton is notable for containing Paleoproterozoic orogens along its margins, herein named the Northern Margin orogen, yet the nature and timing of orogenic and extensional processes of these orogens and their role in the supercontinent cycle remain unclear. In this contribution, we present new field observations, U‐Pb zircon and baddeleyite geochronology dates, and major/trace‐element and isotope geochemical analyses from the northern margin of the North China craton that detail its Paleoproterozoic tectonic and magmatic history. Specifically, we record the occurrence of ca. 2.2–2.0 Ga magmatic arc rocks, ca. 1.9–1.88 Ga tectonic mélange and mylonitic shear zones, and folded lower Paleoproterozoic strata. These rocks were affected by ca. 1.9–1.8 Ga granulite‐facies metamorphism and ca. 1.87–1.78 Ga post‐collisional, extension‐related magmatism along the cratonal northern margin. We interpret that the generation and emplacement of these rocks, and the coupled metamorphic and magmatic processes, were related to oceanic subduction and subsequent continent‐continent collision during the Paleoproterozoic. The occurrence of ca. 1.77–1.73 Ga mafic dykes and ca. 1.75 Ga mylonitic shear zones along the northern margin of the North China craton may have been related to a regional mantle plume event. Our results are consistent with modern style plate tectonics, including oceanic subduction‐related plate convergence and continent‐continent collision, operating in the Paleoproterozoic.

    

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