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1. Thermal Budgets of Magma Storage Constrained by Diffusion Chronometry: the Cerro Galán Ignimbrite

   https://doi.org/10.1093/petrology/egac048  

   Lubbers, Jordan; Kent, Adam J; de Silva, Shanaka (July 2022, Journal of Petrology)

   Abstract The long-term thermochemical conditions at which large bodies of silicic magma are stored in the crust is integral to our understanding of the timing, frequency, and intensity of volcanic eruptions and provides important context for interpreting volcano monitoring data. Despite this, however, individual magmatic systems may exhibit a range of time–temperature paths, or thermal histories, that are the result of many complex and, in some cases, competing processes. This complexity contributes to an incomplete understanding of the long-term thermal evolution of magma stored within the Earth’s crust. Of recent interest to the volcanology community is the length of time large volumes of rheologically eruptible and geophysically detectable magma exist within the crust prior to their eruption. Here we use a combination of diffusion chronometry, trace element, and thermodynamic modeling to quantify the long-term thermal evolution of the 2.08 Ma, 630 km3 Cerro Galán Ignimbrite (CGI) in NW Argentina; one of the largest explosive volcanic eruptions in the recent geologic record. We find that diffusion of both Mg and Sr in plagioclase indicate that erupted magmatic material only spent decades to centuries at or above temperatures (~750°C) required to maintain significant volumes of stored eruptible magma. Calculated plagioclase equilibrium compositions reveal an array of liquids that is controlled overall by fractionation of plagioclase + biotite + sanidine, although high-resolution trace element transects record a diversity of fractionation pathways. Overall, we suggest that there is compelling evidence that the magma erupted from the CGI magmatic system spent most of its upper crustal residence in a largely uneruptible state and was rapidly remobilized shortly before eruption. 

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2. Storage and Evolution of Laguna del Maule Rhyolites: Insight From Volatile and Trace Element Contents in Melt Inclusions

   https://doi.org/10.1029/2020JB019475  

   Klug, Jacob D.; Singer, Brad S.; Kita, Noriko T.; Spicuzza, Michael J. (August 2020, Journal of Geophysical Research: Solid Earth)

   Abstract Interpreting unrest at silicic volcanoes requires knowledge of the magma storage conditions and dynamics that precede eruptions. The Laguna del Maule volcanic field, Chile, has erupted ~40 km³of rhyolite over the last 20 ka. Astonishing rates of sustained surface inflation at >25 cm/year for >12 years reveal a large, restless system. Integration of geochronologic, petrologic, geomorphic, and geophysical observations provides an unusually rich context to interpret ongoing and prehistoric processes. We present new volatile (H₂O, CO₂, S, F, and Cl), trace element, and major element concentrations from 109 melt inclusions hosted in quartz, plagioclase, and olivine from seven eruptions. Silicic melts contain up to 8.0 wt. % H₂O and 570 ppm CO₂. In rhyolites melt inclusions track decompression‐driven fractional crystallization as magma ascended from ~14 to 4 km. This mirrors teleseismic tomography and magnetotelluric findings that reveal a domain containing partial melt spanning from 14 to 4 km. Ce and Cl contents of rhyolites support the generation of compositionally distinct domains of eruptible rhyolite within the larger reservoir. Heat, volatiles, and melt derived from episodic mafic recharge likely incubate and grow the shallow reservoir. Olivine‐hosted melt inclusions in mafic tephra contain up to 2.5 wt. % H₂O and 1,140 ppm CO₂and proxy for the volatile load delivered via recharge into the base of the silicic mush at ~14 to 8 km. We propose that mafic recharge flushes deeper reaches of the magma reservoir with CO₂that propels H₂O exsolution, upward accumulation of fluid, pressurization, and triggering of rhyolitic eruptions. 

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3. Exploring Mid‐to‐Lower Crustal Magma Plumbing of Santorini and Kolumbo Volcanoes Using PmP Tomography

   https://doi.org/10.1029/2025GC012170  

   Autumn, Kaisa R; Hooft, Emilie_E E; Toomey, Douglas R (April 2025, Geochemistry, Geophysics, Geosystems)

   Deep‐crustal magma plumbing at arc volcanoes controls the volume, frequency, and composition of magma being transported to and stored in the upper crust. However, the mid‐to‐lower crust remains a challenging region to image. We explore the mid‐to‐lower crustal velocity structure beneath the Christiana‐Santorini‐Kolumbo Volcanic Field (CSKVF) to better understand how an established stratovolcano and flanking volcano (Santorini and Kolumbo) are fed through the mid‐to‐lower crust. We use active‐source seismic data to obtain a P‐wave velocity model of the crust below the CSKVF. We invert direct and reflected P phases to cover the entire depth extent of the crust and solve for the Moho interface depth. Our model requires a curved Moho interface representative of crustal thickening via underplating. Results show a highV_panomaly in the lower crust under Santorini and a mid‐crustal lowV_panomaly offset from both Santorini and Kolumbo. We find that accumulation of magma is located under the local extensional basin in the upper mid‐crust (<10 km) but is offset at deeper depths. We find evidence for melt storage at 11–13 km depth feeding volcanism at the Kolumbo volcanic chain. This melt is also a plausible source for the 2025 seismic swarm and dike intrusion. Resolution is limited in the mid‐crust below the Santorini caldera, leaving Santorini's mid‐crustal magma plumbing unconstrained. We think it likely that Santorini and Kolumbo have entirely separate crustal plumbing systems and mantle sources, but allow the possibility of a connection in the mid or lower crust. 

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4. Crystals and Melt Inclusions Record Deep Storage of Superhydrous Magma Prior to the Largest Known Eruption of Cerro Machín Volcano, Colombia

   https://doi.org/10.1093/petrology/egae095  

   Castilla, Silvia_C; Newcombe, Megan_E; Piccoli, Philip_M; Peterson, Liam_D (September 2024, Journal of Petrology)

   Abstract Cerro Machín, a volcano located in the northern segment of the Andes, is considered one of the most dangerous volcanoes in Colombia with an explosive record that involves at least five plinian events. Prior studies focused on the last dome-building eruption have suggested the presence of a water-rich mid-crustal magma reservoir. However, no direct volatile measurements have been published and little work has been completed on the explosive products of the volcano. Here, we study the largest known eruption of Cerro Machín volcano which occurred 3600 years BP producing dacitic pyroclastic fall deposits that can be traced up to 40 km from the vent. Lapilli pumice clasts have a mineral assemblage of plagioclase, amphibole, quartz, and biotite phenocrysts, with accessory olivine, Fe–Ti oxides, and apatite. The occurrence of Fo89–92 olivine rimmed by high Mg# amphibole and the established high-water contents in the magma imply the presence of magma near or at water saturation at pressures > ~ 500 MPa. Measurements of up to 10.7 wt % H2O in melt inclusions hosted in plagioclase and quartz in the 3600 years BP eruption products support the idea that Cerro Machín is a remarkably water-rich volcanic system. Moreover, this is supported by measurements of ~103 to 161 ppm H2O in plagioclase phenocrysts. The application of two parameterizations of water partitioning between plagioclase and silicate melt allows us to use our water in plagioclase measurements to estimate equilibrium melt water contents of 5 ± 1 wt % to 11 ± 2 wt % H2O, which are in good agreement with the water contents we measured in melt inclusions. Results of amphibole geobarometry are consistent with a magma reservoir stored in the mid-to-lower crust at a modal pressure of 700 ± 250 MPa, corresponding to a depth of ~25 km. Minor crystallization in the shallow crust is also recorded by amphibole barometry and calculated entrapment pressures in melt inclusions. Amphibole is present as unzoned and zoned crystals. Two populations of unzoned amphibole crystals are present, the most abundant indicate crystallization conditions of 853 ± 26°C (1 se; standard error), and the less abundant crystallized at an average temperature of 944 ± 24°C (1 se). Approximately 18% of the amphibole crystals are normally or reversely zoned, providing evidence for a minor recharge event that could have been the trigger mechanism for the explosive eruption. Plagioclase crystals also show normal and reverse zoning. The moderate Ni concentrations (<1600 μg/g) in the high-Fo olivine xenocrysts suggest that Cerro Machín primary magmas are generated by inefficient interaction of mantle peridotite with a high-silica melt produced by slab melting of basaltic material. Some sediment input is also suggested by the high Pb/Th (>2.2) and Th/La (0.3–0.4) ratios. Whole rock chemistry reveals heavy rare earth element (HREE) depletion and Sr enrichment that likely formed during the crystallization of garnet and amphibole in the upper part of the mantle or lower portion of the crust, promoting the formation of water-rich dacitic magma that was then injected into the middle-to-lower crust. Textural and compositional differences in the crystal cargo that erupted during dome-building and plinian events support the idea that large volumes of magma recharge lead to effusive eruptions, while only small recharge events are needed to trigger plinian eruptions at Cerro Machín. 

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5. Seismic Tomography Reveals a Shared Lower-Crustal Magma Source for Proximal Santorini and Kolumbo Volcanoes

   Autumn, Kaisa R; Hooft, Emilie EE; Toomey, Douglas R (December 2023, 2023 Fall Meeting, American Geophysical Union)

   Santorini volcano in the South Aegean Volcanic Arc has a detailed history of ongoing volcanic and seismic activity, making it a prime location for studying magma storage and transport at arc volcanoes. The shallow magmatic system (<5 km depth) is well constrained by geophysical studies, but the deeper crustal structure is not. Located 15 km NE of Santorini, the Kolumbo seamount is also an active edifice, with consistently more seismicity and hydrothermal venting than Santorini. Geochemical studies indicate that Santorini and Kolumbo are fed by separate mantle and crustal magma sources, but prior seismic studies suggest otherwise (Dimitriadis et al, 2010; McVey et al, 2020). This study addresses the nature of lower-crustal magma structure beneath arc volcanoes and whether evolved volcanoes and nearby vents are connected through their plumbing. Tomographic inversion of P-wave Moho reflection (PmP) and turning P-wave (Pg) traveltimes is used to create 3-D models of Moho depth and P-wave velocity (Vp) down to depths of ~25 km. The PROTEUS experiment provides an exceptionally dense and large aperture traveltime dataset from an amphibious array of ~150 seismometers and ~14,000 active marine sources. The data are ~33,000 manually picked PmP arrivals and ~256,000 Pg arrivals from existing studies. Results show a low Vp anomaly extending from the Moho to the surface. This anomaly starts at the base of the crust under the NW Santorini caldera and extends up to the east. It is most pronounced at 10-15 km depth, where it is offset from both Santorini and Kolumbo. Limited resolution prevents imaging of a connection between this mid-crustal anomaly and the known shallow magma storage region under the Santorini caldera. A high-velocity core beneath Santorini is not found, a feature interpreted at other volcanoes as a cooled intrusive complex. Because no additional low Vp anomalies are found in the lower crust, we infer that a common mantle source and mid-crustal plumbing system is actively feeding both Santorini and Kolumbo. The spatial offset and elongated nature of magma storage implies a complex relationship between evolving magmatic structures and tectonics. 

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