skip to main content


Title: Synthetic Metallodithiolato Ligands as Pendant Bases in [Fe I Fe I ], [Fe I [Fe(NO)] II ], and [(μ-H)Fe II Fe II ] Complexes
Award ID(s):
1665258
PAR ID:
10199338
Author(s) / Creator(s):
; ; ; ; ; ;
Date Published:
Journal Name:
Inorganic Chemistry
Volume:
59
Issue:
6
ISSN:
0020-1669
Page Range / eLocation ID:
3753 to 3763
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. A (PNNP)FeIIcomplex is shown to catalyze the dimerization of terminal alkynesviaa metal–ligand cooperative mechanism.

     
    more » « less
  2. The synthesis, single-crystal structures and magnetic properties of three new cyano-bridged complexes [FeIII4MII2] (M = Fe II , Co II , Ni II ) are reported. Electronic absorption spectroscopy reveals the occurrence of intervalence charge transfer for [FeIII4FeII2]. Field-induced slow magnetic relaxation behavior is exhibited for [FeIII4CoII2] and [FeIII4NiII2] which originates from the ferromagnetic interactions between Fe III and M II spin centers of the square. 
    more » « less