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Title: Synthetic Metallodithiolato Ligands as Pendant Bases in [Fe I Fe I ], [Fe I [Fe(NO)] II ], and [(μ-H)Fe II Fe II ] Complexes
Authors:
; ; ; ; ; ;
Award ID(s):
1665258
Publication Date:
NSF-PAR ID:
10199338
Journal Name:
Inorganic Chemistry
Volume:
59
Issue:
6
Page Range or eLocation-ID:
3753 to 3763
ISSN:
0020-1669
Sponsoring Org:
National Science Foundation
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  1. The synthesis, single-crystal structures and magnetic properties of three new cyano-bridged complexes [FeIII4MII2] (M = Fe II , Co II , Ni II ) are reported. Electronic absorption spectroscopy reveals the occurrence of intervalence charge transfer for [FeIII4FeII2]. Field-induced slow magnetic relaxation behavior is exhibited for [FeIII4CoII2] and [FeIII4NiII2] which originates from the ferromagnetic interactions between Fe III and M II spin centers of the square.