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  • The critical effect of water content in the electrolyte on the reversible electrochemical performance of Zn–VPO 4 F cells
Title: The critical effect of water content in the electrolyte on the reversible electrochemical performance of Zn–VPO 4 F cells
The electrochemistry of the Zn–VPO 4 F system has been studied for the first time in both wet non-aqueous and aqueous zinc-ion electrolytes. It is shown that H + ions present in the electrolyte insert into the cathode host in preference to sluggish Zn 2+ ion insertion. Furthermore, it is demonstrated that while H 2 O as a source of H + is essential for proper cell operation, an aqueous electrolyte is detrimental to cathode stability due to extensive dissolution.  more » « less
Award ID(s):
1709081
PAR ID:
10200292
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Journal of Materials Chemistry A
Volume:
8
Issue:
17
ISSN:
2050-7488
Page Range / eLocation ID:
8262 to 8267
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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