skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Interaction of the (2√3 × 3)rect. Adsorption-Site Basis and Alkyl-Chain Close Packing in Alkanethiol Self-Assembled Monolayers on Au(111): A Molecular Dynamics Study of Alkyl-Chain Conformation
Award ID(s):
1710102
PAR ID:
10209022
Author(s) / Creator(s):
; ; ;
Date Published:
Journal Name:
ACS Omega
Volume:
5
Issue:
23
ISSN:
2470-1343
Page Range / eLocation ID:
13802 to 13812
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Cocrystallization of long-chain bromoalkanes and lipid-like ionic liquids, revealing distinctive host–guest complex structures reminiscent of biomembranes. 
    more » « less
  2. null (Ed.)
    Chiral copper( i ) catalysts are preferred over chiral dirhodium( ii ) catalysts for [3 + 3]-cycloaddition reactions of γ-alkyl-substituted enoldiazoacetates compounds with nitrones. Using the In-SaBox ligand these reactions effectively produce cis -3,6-dihydro-1,2-oxazine derivatives under mild conditions in high yield and with exceptional stereocontrol, and enantioselectivity increases with the size of the γ-substituent. Mechanistic studies show that cycloaddition occurs solely through the formation of ( Z )-γ-substituted metallo-enolcarbene intermediates that are catalytically gennerated from both ( Z )- and ( E )-γ-substituted enoldiazoactates via donor–acceptor cyclopropene intermediates. 
    more » « less