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  • Can Donor Ligands Make Pd(OAc) 2 a Stronger Oxidant? Access to Elusive Palladium(II) Reduction Potentials and Effects of Ancillary Ligands via Palladium(II)/Hydroquinone Redox Equilibria
Title: Can Donor Ligands Make Pd(OAc) 2 a Stronger Oxidant? Access to Elusive Palladium(II) Reduction Potentials and Effects of Ancillary Ligands via Palladium(II)/Hydroquinone Redox Equilibria
Award ID(s):
1953926 1700982
PAR ID:
10223874
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Journal of the American Chemical Society
Volume:
142
Issue:
46
ISSN:
0002-7863
Page Range / eLocation ID:
19678 to 19688
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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    The synthesis of meso-aryl 1,14-dimethoxytripyrrin and tripyrrin-1,14-dione allows isolation of palladium(II) complexes presenting aliphatic C–H bond activation reactivity and multiple ligand-based redox processes. 
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