More Like this

1. Slab-derived devolatilization fluids oxidized by subducted metasedimentary rocks

   https://doi.org/10.1038/s41561-022-00904-7  

   Ague, Jay J.; Tassara, Santiago; Holycross, Megan E.; Li, Ji-Lei; Cottrell, Elizabeth; Schwarzenbach, Esther M.; Fassoulas, Charalampos; John, Timm (March 2022, Nature Geoscience)

   Abstract Metamorphic devolatilization of subducted slabs generates aqueous fluids that ascend into the mantle wedge, driving the partial melting that produces arc magmas. These magmas have oxygen fugacities some 10–1,000 times higher than magmas generated at mid-ocean ridges. Whether this oxidized magmatic character is imparted by slab fluids or is acquired during ascent and interaction with the surrounding mantle or crust is debated. Here we study the petrology of metasedimentary rocks from two Tertiary Aegean subduction complexes in combination with reactive transport modelling to investigate the oxidative potential of the sedimentary rocks that cover slabs. We find that the metasedimentary rocks preserve evidence for fluid-mediated redox reactions and could be highly oxidized. Furthermore, the modelling demonstrates that layers of these oxidized rocks less than about 200 m thick have the capacity to oxidize the ascending slab dehydration flux via redox reactions that remove H₂, CH₄and/or H₂S from the fluids. These fluids can then oxidize the overlying mantle wedge at rates comparable to arc magma generation rates, primarily via reactions involving sulfur species. Oxidized metasedimentary rocks need not generate large amounts of fluid themselves but could instead oxidize slab dehydration fluids ascending through them. Proposed Phanerozoic increases in arc magma oxygen fugacity may reflect the recycling of oxidative weathering products following Neoproterozoic–Palaeozoic marine and atmospheric oxygenation. 

   more » « less
2. Structural Architecture and Attenuation of the Ductile Lower Plate of the Ruby Mountain‐East Humboldt Range Metamorphic Core Complex, Northeast Nevada

   https://doi.org/10.1029/2021TC007162  

   Zuza, Andrew_V; Levy, Drew_A; Dee, Seth; DesOrmeau, Joel_W; Cheng, Feng; Li, Xiangzhong (August 2022, Tectonics)

   Abstract Strongly deformed footwall rocks exposed in metamorphic core complexes (MCC) of the North American Cordillera were exhumed via ductile attenuation, mylonitic shearing, and detachment faulting. Whether these structures accommodated diapiric upwelling or regional extension via low‐angle normal faulting is debated. The Ruby Mountains‐East Humboldt Range MCC, northeast Nevada, records top‐west normal‐sense exhumation of deformed Proterozoic‐Paleozoic stratigraphy and older basement. We conducted 1:24,000‐scale mapping of the southwestern East Humboldt Range, with integrated structural, geochemical, and geochronological analyses to characterize the geometry and kinematics of extension and exhumation of the mylonitized footwall. Bedrock stratigraphy is pervasively intruded by Cretaceous, Eocene, and Oligocene intrusions, but observations of a coherent stratigraphic section show >80% vertical attenuation of Neoproterozoic to Ordovician rocks. These rocks are penetratively sheared with top‐west kinematics. The shear zone thus experienced combined pure‐ and simple‐shear (i.e., general shear) strain. We argue that this shear zone was syn‐/post‐kinematic with respect to Oligocene plutonism because: (a) mylonitic shearing spatially corresponds with preceding Oligocene intrusions; (b) thermochronology reveals that the shear zone experienced substantial cooling and exhumation after Oligocene plutonism; and (c) the mylonites are crosscut by undated, but likely late Oligocene, leucogranite. We propose that Eocene mantle‐derived magmatism and thermal incubation led to Oligocene diapiric upwelling of the middle crust, with ductile stretching focused on the flanks of this upwarp. Regional Basin and Range extension initiated later in the middle Miocene. Therefore, the development of the East Humboldt Range shear zone was not driven by regional extension and coupled detachment faulting. 

   more » « less
3. Temporal changes in diamond formation by subduction throughout Earth history: thermal modeling, seismology, and petrology evidence

   Shirey, Steven B; Smit, Karen V; Pearson, D Graham; Walter, Michael J; Stachel, Thomas (July 2024, Journal of International Kimberlite Conference Abstracts (JIKCA))

   In the current plate tectonic regime, thermal modeling, petrology, and seismology show that subsurface portions of cold slabs carry some of their volatiles into the deep upper mantle, mantle transition zone, and uppermost lower mantle avoiding the devolatilization occurring with normal arc and wedge subduction. Slab crustal remnants at these depths can melt by intersecting their carbonated solidus whereas slab mantle remnants can devolatilize by warming and metamorphosing to ‘dryer’ mineral assemblages. Since fluid release and earthquake production (“dehydration embrittlement”) operates down to ~300 km depths in all subduction zones, we propose, that deep-focus earthquakes trace the places of fluid release at deeper levels (350 to 750 km). Fluids in faults related to earthquake generation will become diamond-forming as they react with mantle rocks along the fault walls. Diamonds thus formed will record deformation produced by mantle convection and slab buckling during mantle storage. Lithospheric diamonds, stored in static ancient continental keels, lack the connection to this type of geodynamic regime that is evident for sublithospheric diamonds. However, a comparison between the two diamond types suggests a geologic model for lithospheric diamond formation in the ancient past. Lithospheric diamonds and sublithospheric diamonds both contain evidence for the recycling of sediments or surficial rocks that have equilibrated at low temperatures with seawater. The known way to inject these materials into diamond-forming regions is slab subduction. Hence both diamond types may have formed by variants of this same process that differ in depth and style over geologic time. Lithospheric diamonds are different from sublithospheric diamonds in critical ways: higher average N content, ages extending into the Paleoarchean, inclusion assemblages indicating formation at lower pressure, and lack of ubiquitous deformation features. Nitrogen content is the key to relating lithospheric diamonds to the subducting slab. Nitrogen occurs in clays and sediments at the slab surface or uppermost crust. Regardless of whether the slab is hot or cold during subduction, nitrogen will be removed into a mantle wedge if one exists. Additionally, diamonds will not survive in the melts/fluids generated in the wedge under oxidizing conditions. For sublithospheric diamonds, their low to non-existent nitrogen content occurs because they are derived from slab fluids/melts once nitrogen has been largely removed or from rocks deeper in the slab where nitrogen is scarce. The much higher nitrogen in lithospheric diamonds suggests that they formed from fluids/melts derived near the slab surface that contained N. In the Archean, such slabs must have subducted close to the nascent mantle keel with no mantle wedge so the fluids could be directly reduced by the mantle keel. We propose a gradual temporal change from shallow, keel-adjacent, mantle-wedge-poor subduction that produced lithospheric diamonds starting in the Paleoarchean to wedge-avoiding, cold and deep subduction that produced sublithospheric diamonds in the Paleozoic. This temporal change is consistent with many geologic features: an early stagnant lid and a buoyant Archean oceanic lithosphere; the slab-imbrication, advective thickening, and diamond-richness of portions of mantle keels; and anomalously diamond-rich ancient eclogites. 

   more » « less
4. Sublithospheric Diamonds; Plate Tectonics from Earth's Deepest Mantle Samples

   https://doi.org/10.1146/annurev-earth-032320-105438  

   Shirey, Steven B; Pearson, D Graham; Stachel, Thomas; Walter, Michael J (July 2024, Annual Review of Earth and Planetary Sciences)

   Sublithospheric diamonds and the inclusions they may carry crystallize in the asthenosphere, transition zone, or uppermost lower mantle (from 300 to ∼800 km), and are the deepest minerals so far recognized to form by plate tectonics. These diamonds are distinctive in their deformation features, low nitrogen content, and inclusions of these major mantle minerals: majoritic garnet, clinopyroxene, ringwoodite, CaSi perovskite, ferropericlase, and bridgmanite or their retrograde equivalents. The stable isotopic compositions of elements within these diamonds (δ11B, δ13C, δ15N) and their inclusions (δ18O, δ56Fe) are typically well outside normal mantle ranges, showing that these elements were either organic (C) or modified by seawater alteration (B, O, Fe) at relatively low temperatures. Metamorphic minerals in cold slabs are effective hosts that transport C as CO3 and H as H2O, OH, or CH4 below the island arc and mantle wedge. Warming of the slab generates carbonatitic melts, supercritical aqueous fluids, or metallic liquids, forming three types of sublithospheric diamonds. Diamond crystallization occurs by movement and reduction of mobile fluids as they pass through host mantle via fractures—a process that creates chemical heterogeneity and may promote deep focus earthquakes. Geobarometry of majoritic garnet inclusions and diamond ages suggest upward transport, perhaps to the base of mantle lithosphere. From there, diamonds are carried to Earth's surface by eruptions of kimberlite magma. Mineral assemblages in sublithospheric diamonds directly trace Earth's deep volatile cycle, demonstrating how the hydrosphere of a rocky planet can connect to its solid interior.▪Sublithospheric diamonds from the deep upper mantle, transition zone, and lower mantle host Earth's deepest obtainable mineral samples.▪Low-temperature seawater alteration of the ocean floor captures organic and inorganic carbon at the surface eventually to become some of the most precious gem diamonds.▪Subduction transports fluids in metamorphic minerals to great depth. Fluids released by slab heating migrate, react with host mantle to induce diamond crystallization, and may trigger earthquakes.▪Sublithospheric diamonds are powerful tracers of subduction—a plate tectonic process that deeply recycles part of Earth's planetary volatile budget. 

   more » « less
5. Record of de-serpentinization and re-serpentinization of an exhumed slab sliver: Implications for fluid circulation in subduction zones

   https://doi.org/10.1016/j.epsl.2025.119213  

   Donoso-Tapia, Damián; Flores, Kennet E; Martin, Celine; Hull, Sarah; Hernández-Uribe, David; Gazel, Esteban (January 2025, Earth and Planetary Science Letters)

   Fluid release associated with serpentinite dehydration (de-serpentinization) during subduction plays a key role in fundamental geological processes such as element transport and recycling, seismicity, and arc magmatism. Although the importance of these fluids is well-known, evidence of de-serpentinization remains scarce in the rock record. Here, we investigated the effects of de-serpentinization and fluid circulation in exhumed metaperidotites from the Raspas Complex (Ecuador). This Early Cretaceous complex records warm subduction (∼13.5 °C/km) and has been hypothesized to represent a coherent slab sliver that preserves the mantle-crust contact (moho) between eclogite-facies metaperidotites and the corresponding crustal section. Petrological observations reveal that titanian-clinohumite-bearing metadunites and banded metaperidotites underwent de-serpentinization after reaching peak pressure–temperatures (P–T) of ∼1.3–1.6 GPa and 620–650 °C. The peak paragenesis is partially obscured by a strong retrograde overprint, driven by crust-derived metamorphic fluids (δ11B ∼ -6 to +8 ‰) that infiltrated at varying fluid/rock ratios, triggering the re-serpentinization of metaperidotites during exhumation (P < 1.3 GPa and 320–400 °C). Thermodynamic forward modeling reveals that fluid release in the Raspas paleo-subduction zone is controlled by brucite breakdown and de-serpentinization, which occur at depths of 25–30 km and ∼50 km, respectively, accounting for a total of up to 10 wt. % H2O of water stored in the rock. Comparatively, dehydration of the crustal section, albeit a minor component, promotes enhanced fluid circulation between 25 and 45 km. During exhumation, circulating crust-derived metamorphic fluids heavily metasomatized the ascending slab sliver and effectively modified its geochemical signature. The depth range of the dehydration reactions overlap the depth of non-volcanic tremors and slow-slip events in warm, active subduction zones worldwide (25–65 km). Thus, the Raspas Complex offers an in-situ window into the fluids responsible for triggering these seismic events. 

   more » « less