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			<titleStmt><title level='a'>Synthesis, characterization, and alkoxide transfer reactivity of dimeric Tl &lt;sub&gt;2&lt;/sub&gt; (OR) &lt;sub&gt;2&lt;/sub&gt; complexes</title></titleStmt>
			<publicationStmt>
				<publisher></publisher>
				<date>02/23/2021</date>
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				<bibl> 
					<idno type="par_id">10226724</idno>
					<idno type="doi">10.1039/d0dt03917a</idno>
					<title level='j'>Dalton Transactions</title>
<idno>1477-9226</idno>
<biblScope unit="volume">50</biblScope>
<biblScope unit="issue">7</biblScope>					

					<author>Amanda Grass</author><author>Lakshani Wathsala Kulathungage</author><author>Duleeka Wannipurage</author><author>Maryam Yousif</author><author>Cassandra L. Ward</author><author>Stanislav Groysman</author>
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			<abstract><ab><![CDATA[Reaction of LiOC              t              Bu              2              Ph with TlPF              6              forms the dimeric Tl              2              (OC              t              Bu              2              Ph)              2              complex, a rare example of a homoleptic thallium alkoxide complex demonstrating formally two-coordinate metal centers. Characterization of Tl              2              (OC              t              Bu              2              Ph)              2              by              1              H and              13              C NMR spectroscopy and X-ray crystallography reveals the presence of two isomers differing by the mutual conformation of the alkoxide ligands, and by the planarity of the central Tl–O–Tl–O plane. Tl              2              (OC              t              Bu              2              Ph)              2              serves as a convenient precursor to the formation of old and new [M(OC              t              Bu              2              Ph)              n              ] complexes (M = Cr, Fe, Cu, Zn), including a rare example of T-shaped Zn(OC              t              Bu              2              Ph)              2              (THF) complex, which could not be previously synthesized using more conventional LiOR/HOR precursors. The reaction of [Ru(cymene)Cl              2              ]              2              with Tl              2              (OC              t              Bu              2              Ph)              2              results in the formation of a ruthenium(              ii              ) alkoxide complex. For ruthenium, the initial coordination of the alkoxide triggers C–H activation at the              ortho              -H of [OC              t              Bu              2              Ph] which results in its bidentate coordination. In addition to Tl              2              (OC              t              Bu              2              Ph)              2              , related Tl              2              (OC              t              Bu              2              (3,5-Me              2              C              6              H              3              ))              2              was also synthesized, characterized, and shown to exhibit similar reactivity with iron and ruthenium precursors. Synthetic, structural, and spectroscopic characterizations are presented.]]></ab></abstract>
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