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			<titleStmt><title level='a'>Next generation electronics on the ultrawide-bandgap aluminum nitride platform</title></titleStmt>
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				<publisher></publisher>
				<date>03/22/2021</date>
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				<bibl> 
					<idno type="par_id">10228158</idno>
					<idno type="doi">10.1088/1361-6641/abe5fd</idno>
					<title level='j'>Semiconductor Science and Technology</title>
<idno>0268-1242</idno>
<biblScope unit="volume">36</biblScope>
<biblScope unit="issue">4</biblScope>					

					<author>Austin Lee Hickman</author><author>Reet Chaudhuri</author><author>Samuel James Bader</author><author>Kazuki Nomoto</author><author>Lei Li</author><author>James C Hwang</author><author>Huili Grace Xing</author><author>Debdeep Jena</author>
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			<abstract><ab><![CDATA[Gallium nitride high-electron-mobility transistors (GaN HEMTs) are at a point of rapid growth in defense (radar, SATCOM) and commercial (5G and beyond) industries. This growth also comes at a point at which the standard GaN heterostructures remain unoptimized for maximum performance. For this reason, we propose the shift to the aluminum nitride (AlN) platform. AlN allows for smarter, highly-scaled heterostructure design that will improve the output power and thermal management of III-nitride amplifiers. Beyond improvements over the incumbent amplifier technology, AlN will allow for a level of integration previously unachievable with GaN electronics. State-of-the-art high-current p-channel FETs, mature filter technology, and advanced waveguides, all monolithically integrated with an AlN/GaN/AlN HEMT, is made possible with aluminum nitride. It is on this new AlN platform that nitride electronics may maximize their full highpower, high-speed potential for mm-wave communication and high-power logic applications.]]></ab></abstract>
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<div xmlns="http://www.tei-c.org/ns/1.0"><head n="1.">Introduction</head><p>As the wireless communication networks that connect our world push to ever-higher frequencies, the performance demand on radio frequency (RF) transistor technology amplifies. The need for higher power, frequency, and efficiency must also comply with the necessity for low cost and small footprint. This strain of competing interests is perhaps highlighted best in the millimeter-wave (mm-wave) frequency range. The mmwave spectrum is at a point of rapid growth and expansion in commercial and military application spaces. This is due to mm-wave's capability for high directionality and its short wavelength, which translates to faster data transmission (&gt; 1 Gbit/s) and higher resolution imaging than lower frequency radio waves.</p><p>Many material platforms are vying for market share in this emerging frequency range. Silicon, bolstered by its maturity and cost-effective scale, has produced output powers up to 1 W in the sub-6 GHz regime with silicon lateral-diffusion metal-oxidesemiconductor (LDMOS) technology <ref type="bibr">[2]</ref>, but struggles at higher frequencies. Successful operation in the mm-wave frequency range has been achieved by gallium arsenide high-electron-mobility transistors (GaAs HEMTs) <ref type="bibr">[3,</ref><ref type="bibr">4]</ref>, silicon germanium heterojunction bipolar transistors (SiGe HBTs) <ref type="bibr">[5]</ref>, and indium phosphide HBTs <ref type="bibr">[6,</ref><ref type="bibr">7]</ref>, albeit at relatively low power levels. To achieve high-power and mm-wave operation simultaneously, focus has turned to gallium nitride (GaN) HEMTs. The relevant material properties of each material platform are shown in Table <ref type="table">1</ref>. GaN's combination of high saturation velocity and wide bandgap enables its high-power, high-frequency performance, and establishes it as the premier material for future mmwave electronics.</p><p>In the past two decades, GaN HEMTs have routinely demonstrated record high power density performance across the GHz frequency range. Initial reports of GaN HEMT performance focused on the conventional metal-polar AlGaN/GaN heterostructures with an emphasis on electric field-shaping metal plates, which allow GaN's breakdown performance to further exceed all other competitive platforms. Among the remarkable power densities demonstrated were 40 W/mm and 30 W/mm at 4 and 8 GHz <ref type="bibr">[8,</ref><ref type="bibr">9]</ref>, respectively. AlGaN/GaN HEMTs have also shown 10.5 W/mm at 40 GHz (higher frequency) <ref type="bibr">[10]</ref>. In an effort to scale for higher frequencies and account for shortchannel effects (SCEs), other heterostructures were introduced, such as InAlN-barrier and InAlGaN-barrier GaN HEMTs, which has demonstrated over 1 W/mm at 94 GHz <ref type="bibr">[11]</ref> and 3 W/mm at 96 GHz <ref type="bibr">[12]</ref>, respectively. Current state-of-the-art performance has been Figure <ref type="figure">1</ref>. A cross-section of the proposed aluminum nitride (AlN) platform. The incorporation of an aluminum nitride buffer will improve upon existing n-type GaN amplifiers, and allow for the inclusion of high-current p-type transistors on the same heterostructure. Aluminum nitride also enables integration of both bulk acoustic wave (BAW) filters and substrate-integrated waveguides (SIW), providing a fully-integrated monolithic RF signal-processing solution. The pFET output characteristics are from Nomoto et al. <ref type="bibr">[1]</ref>. achieved using N-polar GaN HEMTs. By incorporating a thick GaN cap layer, N-polar HEMTs have significantly reduced device dispersion and maintain output powers above 8 W/mm at up to 94 GHz <ref type="bibr">[13,</ref><ref type="bibr">14]</ref>.</p><p>As has historically been the case with developing semiconductor technologies, the laboratory achievements of GaN amplifiers made its first major application appearances in the defense industry. In 2018, Northrup Grumman supplied the first GaNbased ground/air radar system to the U.S. Marine Corps <ref type="bibr">[15]</ref>. The Space Fence, a radar network used to track objects in Earth's orbit made possible with GaN amplifiers, was enabled by Lockheed Martin and declared operational by the U.S. Space Force earlier this year <ref type="bibr">[16]</ref>. GaN is also emerging in commercial spaces, first in 4G-LTE base stations with more broad adaptation expected in 5G and beyond <ref type="bibr">[17,</ref><ref type="bibr">18]</ref>.</p><p>With GaN now rapidly growing in both defense and commercial spaces, it is proper to assess the long-term potential of the current RF GaN heterostructures, with the intention of enabling the maximum performance possible.</p><p>Many of the limitations of conventional GaN amplifiers lie in the foundational layer of the heterostructure -the buffer. While not directly involved in device transport, the buffer material properties have a profound impact on device characteristics and overall performance. In the conventional AlGaN/GaN heterostructure, where the channel is an extension of the GaN buffer, there is a lack of a back barrier to confine the 2DEG in the vertical direction. The consequence is a spreading of channel region into the buffer, with the end result being a significant increase in output conductance, limiting device gain and efficiency in the mm-wave regime. Additionally, buffer leakage currents are common with GaN buffers. AlGaN back barriers were introduced <ref type="bibr">[19,</ref><ref type="bibr">20,</ref><ref type="bibr">21]</ref> to combat this effect, but at the cost of introducing a higher thermal-resistive alloy layer in the path of the heat flow. Heat dissipation continues to be a significant limitation for GaN technology, and the addition of an alloyed backbarrier limits it further.</p><p>It is here, in the juxtaposition of blooming commercial development and an unoptimized GaN amplifier heterostructure, that we propose a new platform for the future of GaN amplifiers: aluminum nitride (AlN). The incorporation of aluminum nitride in the form of a buffer layer will enable next generation performance in three critical ways. (1) Enhance thermal management.</p><p>(2) Provide a maximized back barrier, drastically reducing shortchannel effects (SCEs) and buffer leakage.</p><p>(3) Enable an unprecedented level of integration in nitride electronics.</p><p>The primary integration element enabled by an AlN platform is the addition of the GaN/AlN pchannel FET, allowing for true, high-current nitride CMOS-like RF complementary circuits for the first time in wide bandgap semiconductors <ref type="bibr">[22]</ref>. This is made possible with an AlN/GaN/AlN heterostructure, which produces high density, 2D electron and hole gases simultaneously.</p><p>In addition to enabling nitride CMOS and RF amplifiers on the same platform, AlN also allows for the full integration of passive components. AlN BAW filters, widely adopted in telecommunication front-end modules, can seamlessly integrate via the AlN buffer. Along with signal isolation (BAW filter), computation (CMOS), and amplification (AlN/GaN/AlN HEMT), the AlN platform will also allow for the integration state-of-the-art SiC substrate integrated waveguides (SIWs) for RF signal guidance. The fully realized AlN platform (illustrated in Figure <ref type="figure">1</ref>), with superior AlN HEMT performance potential and unprecedented integration capability, will bolster GaN amplifiers as the forefront technology for the future of mm-wave amplification, and will open the door for an array of new applications previously unachievable with nitride electronics, or any other semiconductor platform.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="2.">Thermal Advantage of Aluminum Nitride</head><p>High-frequency performance of GaN HEMTs stems directly from the fundamental material properties such as band-gap and electron transport. A wide bandgap results in a higher breakdown voltage, and a high electron mobility and saturation velocity of the carrier  An additional factor to consider is the thermal boundary resistance (TBR) between the substrate and the buffer layer. TBR is an intrinsic property of an interface where it acts as a resistance to heat flow and leads to a rise in temperature. In a microscopic picture, according to the diffusive mismatch model (DMM) <ref type="bibr">[25]</ref>, the TBR at a perfect interface between two ideal materials arises due to the difference in phonon density of available states for a heat carrying phonon to scatter into when moving from one material to the other. The calculated TBR between AlN and GaN buffer layers and commonly used Si(111) and SiC substrates are shown in Figure <ref type="figure">2(c</ref>). The Debye density of states approximation has been used. This model predicts that an AlN buffer should have a lower TBR compared to GaN buffer on both SiC and Si substrates, by &#8764; 50% and &#8764; 33% respectively. Experimental measurement of TBRs for these structures have yielded values a couple of orders higher which is attributed to the non-ideal crystal structure near the nucleation interface. This is especially true in case of GaN, where AlN nucleation layers and/or stress-management layers with lower crystal quality result in high TBRs. AlN, with a lower lattice mismatch, can be directly grown on SiC with a better crystal quality and thus lower a TBR. Recent availability of high quality singlecrystal substrates have opened up the possibility of homoepitaxial growth of GaN and AlN on bulk GaN and bulk-AlN substrates respectively, in which TBR will be completely eliminated <ref type="bibr">[28,</ref><ref type="bibr">29]</ref>. Even in this case, comparing to GaN on GaN, AlN on bulk AlN holds a thermal advantage due to higher thermal conductivity.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head>at eri al its elf i n t h e f or m of h e at. T his l e a ds t o a hi g hl y l o c ali z e d ris e i n t e m p er at ur e o n t h e dr ai n si d e of t h e tr a nsist or c h a n n el, w hi c h d et eri or at es t h e el e ctr o ni c pr o p erti es s u c h as m o bilit y, s at ur ati o n v el o cit y, li miti n g t h e m a xi m u m o ut p ut p o w er t h at c a n b e e xtr a ct e d fr o m t h e tr a nsist or. T h e h e ati n g is als o r es p o nsi bl e f or a t h er m al str ess gr a di e nt i n t h e d e vi c e s e mi c o n d u ct or l a y ers w hi c h r e d u c es t h e r eli a bilit y a n d lif eti m e of t h e tr a nsist or. T h er ef or e, it is i m p ort a nt f or a n y hi g h p o w er R F pl atf or m t o e ffi ci e ntl y c o n d u ct t h e h e at a w a y fr o m t h e a cti v e r e gi o n c h a n n el i n or d er t o e n h a n c e t h e p erf or m a n c e. I n a n R F H E M T, t h e dr ai n si d e of t h e g at e, w h er e t h e el e ctri c fi el d p e a ks, a cts as a h e at s o ur c e. I n t h e a bs e n c e of a t o p h e at-c o n d u cti n g l a y er, t h e h e at pri m aril y c o n d u cts t hr o u g h t h e b u ff er, i nt o t h e s u bstr at e a n d t o t h e h e at si n k at t h e b ott o m -as ill ustr at e d i n fi g ur e 2( b). T h e t h er m al r esist a n c es b et w e e n t h e c h a n n el a n d si n k t h er ef or e pl a y a cr u ci al r ol e i n d et er mi ni n g t h e c h a n n el t e m p er at ur e a n d t h er e b y t h e d e vi c e p erf or m a n c e. T h e t h er m al r esist a n c es i n t his s et u p ar e i n t w o f or ms ( 1) (i n v ers e of ) t h er m al c o n d u cti vit y of t h e b u ff er a n d s u bstr at e m at eri als, a n d ( 2) t h er m al b o u n d ar y r esist a n c es b et w e e n t w o m at eri als. B ot h t h es e r esist a n c es ar e m a nif est ati o ns of t h e f u n d a m e nt al p h ysi cs of h e at tr a ns p ort vi a p h o n o ns a n d t h er ef or e ar e i ntri nsi c t o t h e s e mi c o n d u ct or m at eri als if w e c o nsi d er a n i d e al cr yst al m at eri al. T his all o ws us c o m p ar e t h e Al N pl atf or m ( Al N b u ff er o n s u bstr at e), wit h t h e c o n v e nti o n al G a N pl atf or m ( G a N b u ff er o n s u bstr at e) a n d hi g hli g ht t h e a d v a nt a g e w hi c h t h e Al N pr o vi d es us wit h r es p e ct t o t h e e x p e ct e d t h er m al p erf or m a n c e. Fi g ur e 2( a) c o m p ar es t h e e x p eri m e nt all y m e as ur e d t h er m al c o n d u cti vit y v al u es of c o m m o n m at eri als i n III-nitri d e d e vi c es. Sili c o n ( 1 1 1) a n d sili c o n c ar bi d e ( Si C) ar e c o m m o nl y us e d s u bstr at es f or t h es e f a mil y of d e vi c es. Si C, wit h a hi g h t h er m al c o n d u cti vit y of &#8764; 4 2 0 W / m K is t h e s u bstr at e of c h oi c e f or e ff e cti v e t h erm al m a n a g e m e nt i n t h e c urr e nt st at e-of-art R F G a N H E M Ts. Si n gl e-cr yst al di a m o n d [ 2 3] a n d c u bi c-b or o n nitri d e ( c-B N) [ 2 4] h a v e t h e hi g h est t h er m al c o n d u cti viti es a n d t h er e ar e e ff orts t o i nt e gr at e t h es e as c o nd u cti o n / h e at s pr e a di n g l a y ers i n R F H E M Ts</head><p>Thus it is shown how an AlN buffer leads to a better thermal management in RF HEMT when compared to a GaN buffer grown heteroepitaxially on Si, SiC or homoepitaxially on bulk substrates. This should lead to a performance boost in the AlN buffer devices, especially for high power RF transistors. However it must be noted that the values are for near-perfect crystals, and the actual epitaxial crystal quality determines the value of thermal resistances encountered in a real device. Hence the translation of these expected device performance boosts depend heavily on the quality of the material grown.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="3.">Growth of Aluminum Nitride Devices</head><p>The first and important step in the design of any highperformance electronic device is the crystal growth. Research into growth of III-nitrides have a rich history of over 5 decades. Growth of electronics-grade GaN crystals have been investigated and studied from the early days in RCA back in 1960 <ref type="bibr">[30]</ref>. The commonly used epitaxial techniques for growth are metal-organic chemical vapour deposition (MOCVD) and molecular beam epitaxy (MBE). Traditionally in GaN device growths, AlN has been used either as nucleation layers to counter the lattice mismatch between GaN and the substrate and to improve the quality of subsequent layers. AlN is also used as thin barrier/spacer layers in Al(Ga)N/GaN HEMT structures.</p><p>Recent research in electronics-grade AlN growth has been driven by UV LEDs and lasers <ref type="bibr">[31]</ref> on sapphire substrates or bulk single-crystal substrates, and by transistors on AlN platform <ref type="bibr">[32]</ref>. These require much thicker AlN layers than those used in GaN HEMTs, typically 0.5-1 &#181;m.</p><p>Taking a closer look at Al-polar AlN growth for transistor applications, the thick AlN buffer is the essential building-block of the AlN platform. Various groups have demonstrated the growth of AlN buffer layers for HEMTs using MOCVD <ref type="bibr">[33]</ref>, plasma-assisted (PA) MBE <ref type="bibr">[34]</ref>, ammonia (NH 3 ) MBE <ref type="bibr">[35]</ref>. The AlN layers have been grown on various substrates such as MOCVD-grown AlN on Sapphire templates <ref type="bibr">[36]</ref>, 6H-SiC <ref type="bibr">[37]</ref> and Bulk single crystal AlN <ref type="bibr">[34]</ref> as starting substrates. 6H-SiC is typically the substrate of choice for high-power RF transistors due to its low lattice mismatch with respect to AlN, high thermal conductivity and availability of large wafers. Furthermore, it opens up the unique prospect of integration with substrate integrated waveguide technologies (SIW) using through substrate vias (TSVs). Typical dislocation densities in devices on MBE-grown 1 &#181;m thick AlN buffers on 6H-SiC range in &#8764; 10 9 cm -2 . It must be noted that fully-strained AlN on SiC films up to 700 nm have been demonstrated with threading dislocation densities in the mid 10 8 cm -2 <ref type="bibr">[38]</ref>. Reducing the dislocation densities should reduce the gate leakage in Schottky gated transistors, translating to high on-off ratios.</p><p>Recent efforts in MBE have successfully demonstrate high-quality homoepitaxial AlN on single crystal AlN substrates <ref type="bibr">[28,</ref><ref type="bibr">29]</ref> by optimized crystal surface cleaning.</p><p>Because of its wide bandgap and high activation energies of impurity dopants, these AlN layers are electrical insulators and show low buffer leakage in a transistor. On top of this buffer, an active region with a 2D electron gas (2DEG) is grown for n-channel devices, as shown in figure <ref type="figure">3</ref>. A GaN layer, typically 20-200nm thick, is used as the channel layer. GaN layers up to 30 nm thick have been shown to be psuedomorphically strained to the AlN buffer. An AlN barrier then grown on top generates a high-density 2DEG at the AlN/GaN interface of densities &#8764; 2 -4 &#215; 10 13 cm -2 . The channel thickness and the barrier thickness are independent knobs to tune the 2DEG density. Typical room temperature Hall mobilities in these 2DEGs have A c c e p t e d M a n u s c r i p t been measured to be around &#8764; 700 cm 2 /V &#8226; s at high densities of &#8764; 2 -3 &#215; 10 13 cm -2 <ref type="bibr">[37,</ref><ref type="bibr">34,</ref><ref type="bibr">35]</ref>. Even though this number is lower than mobilites (&#8764; 1800 cm 2 /V &#8226; s reported for lower density 2DEG (mid-10 12 cm -2 ) in GaN HEMTs, the high charge densities and high conductivities enable low R ON and high oncurrent densities in AlN/GaN/AlN HEMTs <ref type="bibr">[37]</ref>. A few groups have also demonstrated a higher mobility 2DEG &#8764; 1400-2000 cm 2 /V &#8226; s at a 2DEG density of &#8764; 1&#215;10 13 cm -2 using an AlGaN barrier instead of AlN barrier <ref type="bibr">[33,</ref><ref type="bibr">39]</ref>. This gives up the advantage of having a relaxed barrier which is preferred for the reliability of a RF HEMT.</p><p>The AlN buffer also offers a unique platform for p-channel transistors due to the ability to generate a high density two-dimensional hole gas (2DHG) at the GaN channel/AlN buffer interface <ref type="bibr">[40]</ref>. This is the ptype analog of the Al(Ga)N/GaN n-channel HEMT structure. It does not need any acceptor doping to generate holes. An undoped GaN/AlN heterostructure exhibits a hole density of &#8764; 5 &#215; 10 13 cm -2 and Hall mobility of 25 cm 2 /V &#8226; s at room temperature.</p><p>The presence of both a high-density 2DEG and 2DHG on the same platform makes it very attractive for wide-bandgap CMOS devices. Record p-channel <ref type="bibr">[1]</ref> and n-channel devices <ref type="bibr">[41]</ref> have been demonstrated on this platform.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="4.">AlN/GaN/AlN Power Amplifier</head><p>Thoughtful III-Nitride heterostructure design is the foundation upon which all high-power, mm-wave devices must be built. As previously mentioned, aluminum nitride is the premier III-nitride buffer material, as it simultaneously confines the 2DEG and 2DHG, electrically insulates, and thermally conducts better than GaN. Equally as important for mm-wave performance is the material choice for the top barrier. For RF amplifiers, high transconductance and gain are critical, and it is therefore necessary to scale the barrier as thin as possible. This is where material choice is key, as the top barrier material can limit vertical scaling by requiring a certain thickness to generate sufficient charge density.</p><p>To quantify this, a self-consistent 1D Schrodinger-Poisson solver <ref type="bibr">[42]</ref> was used to simulate the barrier thickness required to generate a 2DEG high density of 2 &#215; 10 13 cm -2 for AlGaN, InAlN, and AlN top barriers on Ga-polar GaN channels. The Al 0.3 Ga 0.7 N barrier, even at 20 nm thick, is unable to achieve the desired high density 2DEG, instead showing 1.4 &#215; 10 13 cm -2 . Also popular in contemporary GaN HEMT design is the InAlN barrier. In 0.17 Al 0.83 N fares better, generating a 2&#215;10 13 cm -2 2DEG at a barrier thickness of 6 nm. Notably, an AlN top barrier of just 1.4 nm able to meet the 2 &#215; 10 13 cm -2 2DEG threshold. This reduction is due to the increased polarization difference at the AlN/GaN interface. While the necessary AlN thickness will change slightly when the AlN top barrier and GaN channel are strained to an AlN buffer, this simple comparison is used to demonstrate the general scalability of AlN versus other common top barrier semiconductors. The reduced top barrier thickness provided by AlN is critical for future ultra-scaled mmwave devices, as it has been empirically shown that transconductance rapidly falls off when the gate length to barrier thickness ratio (L G : t b ) is less than five <ref type="bibr">[43]</ref>. This is due to short channel effects (SCEs) that can be attributed to the lack of gate control, as a result of the increased distance between the gate and the   2DEG. It is important to note that SCEs are also heavily dependent on the presence of a back barrier, and that both a back barrier and thin top barrier are necessary to effectively mitigate SCEs for ultra-scaled HEMTs. While L G /t b &lt; 5 may shift depending on the full heterostructure design, it can serve as a ruleof-thumb for the gate length limit for commerciallyviable device design. Going off this rule, to achieve RF devices with a high density 2DEG and without significant SCEs, an AlGaN barrier will require an L G of 100 nm, and InAlN requires L G = 30 nm. This is a clear limiting factor, as gate lengths as short as 20 nm have already been demonstrated in industry <ref type="bibr">[44]</ref>. With an ideal AlN top barrier of 1.4 nm, and accounting for the fact that the centroid of the 2DEG is &#8764;1 nm from the interface, SCEs can be prevented to a gate length of 10 nm. To maximize vertical scaling capabilities, and to take advantage of state-of-the-art, already available gate technology, an aluminum nitride top barrier is advantageous.</p><p>The incorporation of AlN in both the top barrier and buffer results in an AlN/GaN/AlN heterostructure.</p><p>Devices on this heterostructure, grown by molecular beam epitaxy (MBE), were first demonstrated in 2012 <ref type="bibr">[32]</ref>.</p><p>In this report, the GaN channel is scaled to 30 nm in thickness. This improves confinement of the 2DEG and minimizes the distance from the active region to the more thermally conductive AlN buffer. Another effect of having a thin GaN channel is that it can be psuedomorphically strained to the AlN buffer <ref type="bibr">[45]</ref>. This translates up through the GaN channel to the AlN top barrier, resulting in a relaxed top barrier that increases device reliability and is capable of preventing significant leakage currents at a thickness of just 1 nm <ref type="bibr">[46]</ref> due to the high conduction band offset between GaN and AlN.</p><p>Perhaps most critically for high-power, mm-wave applications, AlN boasts the largest bandgap, and therefore the largest critical electric field, of the  III-nitrides. This is advantageous for increasing device breakdown, which can dramatically increase the maximum output power.</p><p>Accordingly, the breakdown characteristics of AlN/GaN/AlN HEMTs were investigated for gate-drain lengths (L GD ) ranging from 0.27 to 5.1 &#181;m <ref type="bibr">[37]</ref>. For RF amplifiers, the breakdown voltage metric is defined as the voltage at which I D &#8805; 1 mA/mm. The devices were covered in Fluorinert during the measurement process. Figure <ref type="figure">5</ref>(a) shows the three terminal off-state breakdown of three AlN/GaN/AlN HEMTs with varied gate-drain distances. Among all devices, the highest breakdown voltage observed is V BD = 591 V (L GD = 5.1 &#181;m), corresponding to an average electric field (E BD ) of 1.16 MV/cm. All measured devices had average electric fields above 1 MV/cm at breakdown, with 80% of RF devices showing average breakdown fields above 1.5 MV/cm and up to 2 MV/cm. Prior to breakdown, the gate current is found to be roughly equal to the drain current. As a result the breakdown is likely due to gatedrain leakage and not avalanche or channel breakdown, and therefore is far from the material limits. While the breakdown mechanics of GaN HEMTs in general are still not fully understood, the consistently high breakdown fields observed in AlN/GaN/AlN HEMTs are promising for the RF amplifier potential of the heterostructure. The high breakdown voltage translates to high operating voltage, as demonstrated by the small-signal performance at a drain bias of 30 V, benchmarked in Figure <ref type="figure">5</ref>(c), yielding a Johnson figure of merit value of 2.2 THz&#8226;V.</p><p>More recently, AlN/GaN/AlN HEMTs were fabricated for large-signal amplification measurements. The AlN/GaN/AlN heterostructure was grown by MBE on 6H-silicon carbide substrates. The fabrication process for the AlN/GaN/AlN HEMTs is highlighted by MBE-regrown ohmic contacts and electron beam lithography (EBL) defined T-gates. The regrowth process begins by patterning the regrown contact regions with a chromium/silicon dioxide hardmask. The sample is then etched via a chlorine-based inductively coupled plasma (ICP) to expose the 2DEG from the sides. The sample is loaded into the MBE where heavily n-type doped ([Si] &#8764; 10 20 cm -3 ) GaN is regrown to form an ohmic contact to the 2DEG. The hardmask is removed by a buffer oxide etch. This regrowth process produced a contact resistance of 0.23 &#8486;&#8226;mm. The T-gated devices showed oncurrents up to 3.3 A/mm, as shown in Figure <ref type="figure">6(a)</ref>. This high on-current is achieved with an AlN-top barrier thickness of 4 nm and a corresponding charge density of 3&#215;10 13 cm -2 . Small-signal measurements were performed across a range of gate and drain bias points, with the best single bias-point cutoff frequency (f t ) and maximum oscillation frequency (f max ) of 140 and 239 GHz, respectively. Finally, initial largesignal measurements were performed for these devices, yielding a high power added efficiency (PAE) of 55% and a corresponding output power (P out ) of 2.8 W/mm at 6 GHz. The output current density at this PAE/P out was 500 mA/mm. These initial devices were limited by gain compression, a product of immature fabrication processes, including but not limited to unoptimized SiN-last passivation.</p><p>The long-term solution to the unoptimized SiN is in-situ passivation, deposited during the MBE growth of the heterostructure. Efforts are currently underway to significantly increase the thickness of the top AlN barrier (&gt;20 nm), which will move the surface significantly further away from the channel, mitigating dispersion and subsequent gain compression. In this case, a recessed gate contact will be used to maintain gain at mm-wave frequencies.</p><p>While process immaturity currently limits the output power of RF transistors on the AlN platform, the large breakdown, near-record on-currents, promising small-signal measurements, and high PAE, are indica-</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head>A c c e p t e d M a n u s c r i p t</head></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head>Figures for SST Spl Ed 11</head><p>Figure <ref type="figure">7</ref>. The 2D hole gas in GaN/AlN heterostructures compared to other reported 2DHGs on in III-nitrides. Note that the only 2DHG reported so far in a heterostructure without acceptor doping is the GaN/AlN 2DHG <ref type="bibr">[40]</ref>. Comparison to other hole gases on other platforms can be found in Chaudhuri et al. <ref type="bibr">[40]</ref>.</p><p>tive of much higher potential. This combined with an optimized heterostructure capable of the most aggressive vertical scaling, suggest that the AlN/GaN/AlN HEMT will soon be capable of much higher output power (&gt; 10 W/mm) at mm-wave frequencies.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="5.">AlN-based CMOS</head><p>The prospect of wide-bandgap CMOS, particularly in nitrides, has been limited by the physics and development of the p-type conductivity <ref type="bibr">[22]</ref>. Difficulties for GaN p-type technology are rooted in the heavy valence band effective masses (low mobility) and deep valence energies (hard to contact). Furthermore, the large acceptor ionization energy (150-200 meV for Magnesium <ref type="bibr">[47]</ref>) results in poor dopant activation efficiencies of less than 5%. While numerous structures (GaN/AlGaN, GaN/AlInGaN, InGaN/GaN) have used polarization to induce hole gases, it is only on the AlN platform, using a relatively simple Ga-polar GaN/AlN heterostructure, that a 2DHG has been successfully demonstrated in nitrides without the use of acceptor doping <ref type="bibr">[40]</ref>. This is the p-type analog of the ubiquitous Al(GaN)N/GaN 2DEG which serve as the channel for RF HEMTs.</p><p>Another issue for GaN p-channels is the low hole mobility compared to electrons, with phonon scattering restricting the room-temperature hole mobilities <ref type="bibr">[48,</ref><ref type="bibr">49]</ref> to &#8764;50 cm 2 /V &#8226; s (compared to &#8764; 1000 -1800 cm 2 /V &#8226; s in GaN 2DEGs). Therefore, in order to minimize sheet resistance, most of the heavy lifting must come from the carrier density. In the same manner as the n-type devices, the GaN/AlN interface provides the maximized polarization difference, and has generated 2DHGs densities of &#8764; 5 &#215; 10 13 cm -2 , among the highest reported among III-nitrides, as shown in Figure <ref type="figure">7</ref>.</p><p>A more practical, yet just as significant, hurdle to commercial realization of GaN CMOS is the ease of integration of the n-type and p-type devices. In p-type heterostructures that require doping and/or multichannel structures, it is difficult to produce quality, high-density, and easily accessible 2DHGs and 2DEGs on the same heterostructure. Fortunately, the same AlN/GaN/AlN heterostructure used to produce the nchannel FET/HEMT results also contains the exact GaN/AlN interface which has yielded the high 2DHG carrier densities shown in Figure <ref type="figure">7</ref>. It has been demonstrated <ref type="bibr">[50]</ref> that after a low-power ICP/RIE etch to remove the top AlN barrier layer, the 2DEG is eliminated and only the 2DHG remains, which is reflected in the Hall conductivity changing from n-type to p-type. It is proper to acknowledge that integration challenges remain in this scheme, such as achieving low resistance contacts to an etch-exposed p-channel and recess etch control. Still, it is the combination of simplicity of the heterostructure and quality of the 2DEG and 2DHG that offers a real chance at highperformance nitride CMOS, and it is enabled by the AlN platform.</p><p>Since the first demonstration, the GaN/AlN pchannel FET (pFET) has shown continuous improvement with device processing iterations. The first GaN/AlN pFET was demonstrated in 2012 <ref type="bibr">[52]</ref>, with  <ref type="bibr">[51,</ref><ref type="bibr">22]</ref> on-currents over -100 mA/mm when the device was pushed to -40 V drain bias, and was limited to 3x on/off ratio. In 2019, pFETs showed high current performance within a reasonable bias range, with the drain current in excess of -100 mA/mm at -10 V drain bias <ref type="bibr">[51]</ref>. More recently, pFET devices on the GaN/AlN platform have demonstrated a record high on-current of 0.42 A/mm <ref type="bibr">[1]</ref>, as shown in Figure <ref type="figure">9</ref>(a). The peak transconductance of 66 mS/mm was observed with two orders of on/off modulation (Figure <ref type="figure">9(b)</ref>). This on/off ratio on this Schottky-gated device is limited by gate leakage. The tuning of the gate placement, surface treatment, and incorporation of a high-K dielectric will dramatically reduce leakage while retaining the overall device performance. The high 2DHG density, in com-bination with a p-InGaN cap layer below the ohmic contact metal (Figure <ref type="figure">8(a</ref>,<ref type="figure">c</ref>)), achieved an extremely low p-type contact resistance of 1 &#8486;&#8226;mm when the current is in excess of 100 mA/mm. A cross section of the device, as well as a benchmark of on-current achieved in nitride pFETs, are shown in Figure <ref type="figure">8</ref>. The on-current of 0.42 A/mm is an order of magnitude higher than the next closest nitride pFET platform. In addition to oncurrent, the GaN/AlN pFET has also set the record for small-signal gain in p-channel GaN devices, with a cutoff frequency (f t ) and maximum oscillation frequency (f max ) of 19.7 and 23.3 GHz, respectively, as shown in Figure <ref type="figure">9</ref>(c). The previous record for small-signal gain in p-channel GaN devices was 0.2 and 0.64 GHz <ref type="bibr">[53]</ref>.</p><p>As the GaN/AlN pFET on-current approaches the A c c e p t e d M a n u s c r i p t same order of magnitude as the AlN/GaN/AlN HEMT devices, it should finally become possible to match n and p current drives (at reasonable width ratio) in III-nitrides. The combination of current-matched devices and pFETs with f t , f max approaching mmwave frequencies, made possible with the AlN platform, will open up wide-bandgap CMOS design space and enable new applications previously not possible with GaN.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="6.">Bulk Acoustic Wave (BAW) Filter Integration</head><p>RF communication systems consist of a transmit (Tx) and receive (Rx) module.</p><p>The transmit module consists of a high power amplifier (PA) to create and emit high-frequency electromagnetic waves. This need is met by high-power, high-frequency transistors based on a semiconductor platform suited to the frequency and power needs. The kinds discussed earlier in this article using AlN/GaN nitride semiconductors offer a solution for the high-frequency and high-power window, in the mm-wave regime. As essential as to transmit is to be able to receive the signal to which noise has been added during transmission, and whose strength has diminished substantially by the time it is captured by an antenna. To boost the signal back, low-noise amplifiers (LNAs) are needed in the receive module. LNAs are active transistors that may be designed slightly differently from the high-power PAs to boost this regime of performance. But there is a need to first discern the frequency of the signal from the noise in several other frequencies that enter the receiver antenna. For this purpose, passive filters are used. In the mm-wave exceeding 100 GHz, substrateintegrated waveguides (SIWs) are used, which are discussed in the next section. This section describes the filters at lower frequencies, of 10 GHz or lower, that form the front-end of receiver modules in this frequency range. Aluminum nitride plays a major role in this application because of its mix of attractive piezoelectric and dielectric properties, combined with compatibility with CMOS back-end of the line (BEOL) processing restrictions. In those applications, AlN is deposited by sputtering on the silicon platform to fabricate the filters. Increasingly, the fact that AlN is also grown epitaxially for GaN/AlN transistors is being investigated to approach this problem from the opposite end.</p><p>Here we discuss the unique opportunities and challenges in making this form of epitaxial integration of BAW with nitride electronics possible.</p><p>The AlN BAW filter operates by forming a metalinsulator-metal acoustic cavity whose thickness determines the desired filter center frequency. Because of the piezoelectric property of AlN, the electromagnetic wave is converted to a sound wave of much smaller wavelength, while conserving the frequency, and thus the cavity resonator only allows those wavelengths that fit to pass through, rejecting the others. The figure of merit of this behavior is the product k 2 Q, where k 2 is the electromechanical coupling coefficient, and Q is the quality factor of the resonator. Typical values for AlN BAW filters are k 2 &#8764; 0.08 and Q &#8764; 5000 in the 1-10 GHz window. Since the thickness of AlN required to move to higher frequencies becomes deep sub-micron, the crystalline quality of the conventional sputtering technique poses significant challenges. The crystalline AlN used in nitride FETs and UV LEDs and Lasers have on the other hand managed to produce high quality AlN within 100 nm from the growth interfaces. Therefore, a significant opportunity exists to exploit the epitaxial-AlN for fabricating BAWs. This method has initially been explored <ref type="bibr">[54,</ref><ref type="bibr">55]</ref>, and more recently even the metal electrodes have been deposited by epitaxy, realizing an all-epitaxial EpiBAW structure using NbN/AlN/NbN heterostructures <ref type="bibr">[56]</ref>. While this is primarily in the demonstration phase, significant challenges lie ahead to harness its true potential. The challenges are not just in the crystalline and piezoelectric control of the epitaxial AlN layers, but in avoiding undesired lateral edge modes, and most importantly, controlling the resistance of the metal electrodes, whose thickness must also be scaled in tandem with the thickness of the AlN layers themselves.</p><p>The more interesting opportunity afforded by the EpiBAW structures is the potential to directly integrate them with the AlN/GaN/AlN HEMTs (and also the pFETs and the nitride CMOS) which are described earlier in this article. The on-chip nitride CMOS can then perform low-level of digital logic operations on the nitride chip, before handing off the heavy signal processing to the CMOS back end in the receiver, by taking advantage of the direct integration afforded by the AlN platform. But for moving to the 100 GHz window, the resistive losses of the BAW seem insurmountable at this point since the metal electrodes must be shrunk to a few nm thickness. But luckily the ability to integrate waveguide filters is both feasible and attractive, as discussed next.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="7.">AlN for Substrate Integrated Waveguides</head><p>AlN has been widely used in packaging electronic devices and circuits, including those of RF and microwave electronics. Moving up to mm-wave, the relatively high dielectric constant (k) of AlN compared to that of quartz, glasses or polymers can be turned into an advantage in reducing the interconnect size in microwave monolithically integrated circuits (MMICs), A c c e p t e d M a n u s c r i p t which are necessary for high-density phased arrays. For example, substrate-integrated waveguides (SIWs) have been developed mainly on printed circuit boards for RF and microwave electronics <ref type="bibr">[57,</ref><ref type="bibr">58]</ref>. Above 100 GHz, SIW can be realized on chip for mmwave MMICs, whether the AlN layer is grown on a native substrate or on other high-k substrates such as SiC, Si or sapphire. This is because, the width of an SIW, approximately one half of the signal wavelength, is less than 1 mm above 100 GHz in highk substrates, making the SIW small enough to be realized on chip. Although these high-k substrates have comparable dielectric constants and loss tangents (Table <ref type="table">I</ref>), AlN and SiC SIWs are particularly attractive for high-power nitride electronics because of their high thermal conductivities. Additionally, they have closely matched temperature coefficients of expansion for avoiding thermally induced stress in high-power electronics. Their mechanical toughness ensures high yield for SIWs made of hundreds of through-substrate vias (TSVs). Note that the TSV process is well developed for Si, AlN and SiC. To date, most MMICs use microstrip or coplanar waveguides as interconnects, in which the current is confined along narrow metal lines. By contrast, the current is spread throughout the cross section of an SIW, resulting in higher power-handling capacity. Being well enclosed by metal TSVs and films, the SIW has negligible radiation and crosstalk, which are critical for interconnects above 100 GHz. In fact, the SIW loss is dominated by the metal conductor loss instead of radiation loss or dielectric loss. This is also why SIWs with less than 0.5 dB/mm total loss around 140 GHz has been demonstrated in high-resistivity Si <ref type="bibr">[59]</ref> and SiC <ref type="bibr">[60]</ref>, although they are not true insulators. It has also been shown that the SiC SIW is three times less lossy than microstrip or coplanar waveguides made of the same material. Lastly, with increasing frequency, the loss of the SIW decreases whereas the loss of the microstrip or coplanar waveguide increases.</p><p>Beyond low-loss and high-power interconnects, SIWs can be used as high-quality impedance transformers, filters, and antennas, which are critical com-ponents in high-power electronics but traditionally difficult to be integrated on chip. Impedance transformers can be readily realized by adding tuning TSVs in an SIW. By coupling a tuning TSV to a piezoelectrically controlled AlN varactor, tunable filters can be realized similar to that realized in quartz SIWs at the Ka band <ref type="bibr">[61]</ref>. SIW antennas are naturally edge emitters <ref type="bibr">[62]</ref>, which are more suitable for high-power phased arrays than surface emitters, giving the heat dissipation requirements.</p></div>
<div xmlns="http://www.tei-c.org/ns/1.0"><head n="8.">Conclusion</head><p>The rapid advancements of GaN HEMTs in power and efficiency at mm-wave frequencies have enabled its prominent role in a variety of future wireless communication systems. This article has provided an overview of how aluminum nitride may enhance that role via improved HEMT design and new possiblities for nitride integration. The combination of optimized GaN amplifier performance, near current-matched nitride CMOS, and state-of-the-art BAW filters and SIWs, all on the same thermally-conductive AlN platform, will bring digital logic and analog systems together on one, fully-integrated high-power chip. The hope of this AlN-enabled system is to unlock new application spaces previously untouched by GaN electronics, and to get a glimpse of the full potential of the III-nitride material system. </p></div></body>
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