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			<titleStmt><title level='a'>Synthesis and crystallographic characterization of diphenylamide rare-earth metal complexes &lt;i&gt;Ln&lt;/i&gt; (NPh &lt;sub&gt;2&lt;/sub&gt; ) &lt;sub&gt;3&lt;/sub&gt; (THF) &lt;sub&gt;2&lt;/sub&gt; and [(Ph &lt;sub&gt;2&lt;/sub&gt; N) &lt;sub&gt;2&lt;/sub&gt; &lt;i&gt;Ln&lt;/i&gt; (μ-NPh &lt;sub&gt;2&lt;/sub&gt; )] &lt;sub&gt;2&lt;/sub&gt;</title></titleStmt>
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				<publisher></publisher>
				<date>09/01/2020</date>
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				<bibl> 
					<idno type="par_id">10232083</idno>
					<idno type="doi">10.1107/S2056989020009998</idno>
					<title level='j'>Acta Crystallographica Section E Crystallographic Communications</title>
<idno>2056-9890</idno>
<biblScope unit="volume">76</biblScope>
<biblScope unit="issue">9</biblScope>					

					<author>Chad T. Palumbo</author><author>Christopher M. Kotyk</author><author>Joseph W. Ziller</author><author>William J. Evans</author>
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			<abstract><ab><![CDATA[Studies of the coordination chemistry between the diphenylamide ligand, NPh              2              , and the smaller rare-earth              Ln              III              ions,              Ln              = Y, Dy, and Er, led to the structural characterization by single-crystal X-ray diffraction crystallography of both solvated and unsolvated complexes, namely, tris(diphenylamido-κ              N              )bis(tetrahydrofuran-κ              O              )yttrium(III), Y(NPh              2              )              3              (THF)              2              or [Y(C              12              H              10              N)              3              (C              4              H              8              O)              2              ],              1-Y              , and the erbium(III) (Er),              1-Er              , analogue, and bis[μ-1κ              N              :2(η              6              )-diphenylamido]bis[bis(diphenylamido-κ              N              )yttrium(III)], [(Ph              2              N)              2              Y(μ-NPh              2              )]              2              or [Y              2              (C              12              H              10              N)              6              ],              2-Y              , and the dysprosium(III) (Dy),              2-Dy              , analogue. The THF ligands of              1-Er              are modeled with disorder across two positions with occupancies of 0.627(12):0.323(12) and 0.633(7):0.367(7). Also structurally characterized was the tetrametallic Er              III              bridging oxide hydrolysis product, bis(μ-diphenylamido-κ              2              N              :              N              )bis[μ-1κ              N              :2(η              6              )-diphenylamido]tetrakis(diphenylamido-κ              N              )di-μ              3              -oxido-tetraerbium(III) benzene disolvate, {[(Ph              2              N)Er(μ-NPh              2              )]              4              (μ-O)              2              }·(C              6              H              6              )              2              or [Er              4              (C              12              H              10              N)              8              O              2              ]·2C              6              H              6              ,              3-Er              . The              3-Er              structure was refined as a three-component twin with occupancies 0.7375:0.2010:0.0615.]]></ab></abstract>
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