- Award ID(s):
- 2000391
- NSF-PAR ID:
- 10249192
- Date Published:
- Journal Name:
- Progress in Polymer Science
- Volume:
- 111
- Issue:
- C
- ISSN:
- 0079-6700
- Page Range / eLocation ID:
- 101311
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract The first well‐controlled aqueous atom‐transfer radical polymerization (ATRP) conducted in the open air is reported. This air‐tolerant ATRP was enabled by the continuous conversion of oxygen to carbon dioxide catalyzed by glucose oxidase (GOx), in the presence of glucose and sodium pyruvate as sequential sacrificial substrates. Controlled polymerization using initiators for continuous activator regeneration (ICAR) ATRP of oligo(ethylene oxide) methyl ether methacrylate (OEOMA,
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